802425

2-Bromo-1,10-phenanthroline

• Empirical Formula (Hill Notation): C₁₂H₇BrN₂
• CAS Number: 22426-14-8
• Molecular Weight: 259.10
• NACRES: NA.22
• PubChem Substance ID: 329768737
• UNSPSC Code: 12352100
• MDL number: MFCD13152102
• Form: powder

Properties

• form: powder
• Quality Level: 100
• mp: 160-165 °C
• functional group: bromo
• SMILES string: BrC1=NC2=C(N=CC=C3)C3=CC=C2C=C1
• InChI: 1S/C12H7BrN2/c13-10-6-5-9-4-3-8-2-1-7-14-11(8)12(9)15-10/h1-7H
• InChI key: ZRJUDAZGVGIDLP-UHFFFAOYSA-N

Description

Application

Brominated phenanthroline can be synthesized via a method reported by Baran and coworkers using a two-step protocol through N-Oxide formation using m-CBPA (Aldrich 273031) and bromination using TBAB (Sigma-Aldrich 426288) and p-Toluenesulfonic anhydride (Aldrich 259764).

Other Notes

Regioselective Bromination of Fused Heterocyclic N-Oxides

Safety Information

• pictograms: GHS06,GHS05,GHS09
• signalword: Danger
• hcodes: H301,H315,H318,H410
• pcodes: P273 - P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310
• Hazard Classifications: Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable