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289787

Sigma-Aldrich

Copper(II) hydroxide

technical grade

Synonym(s):

Cupric hydroxide

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About This Item

Linear Formula:
Cu(OH)2
CAS Number:
20427-59-2
Molecular Weight:
97.56
EC Number:
243-815-9
MDL number:
MFCD00010968
UNSPSC Code:
12352302
PubChem Substance ID:
24857213
NACRES:
NA.23

grade

technical grade

Quality Level

100

form

powder

contains

stabilizer

concentration

≥57.0% Cu (EDTA titration)

solubility

H2O: insoluble(lit.)
aqueous acid: slightly soluble(lit.)

application(s)

battery manufacturing

SMILES string

O[Cu]O

InChI

1S/Cu.2H2O/h;2*1H2/q+2;;/p-2

InChI key

JJLJMEJHUUYSSY-UHFFFAOYSA-L

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General description

The orthorhombic nature of copper hydroxide crystals was determined by X ray diffraction. Copper hydroxide can act as a heterogeneous catalyst in the selective oxidative cross coupling of terminal alkynes to yield their corresponding ynamides.

Application

Copper hydroxide based monoliths can be used in the synthesis of copper hydroxide-based monolithic xerogels. Potential applications of this metal organic frameworks (MOFs) include gas storage, separation, drug delivery, and biomedicine. Supported Cu(OH)x can be used as a catalyst for the aerobic cross dehydrogenative coupling of benzenethiols and cyclic amides to yield N-acylsulfenamides.

Signal Word

Danger

Hazard Statements

H302,H318,H330,H410

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW7667
MKCV7615
MKCV0393
MKCV0475
MKCS8124

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Heterogeneously catalyzed selective aerobic oxidative cross-coupling of terminal alkynes and amides with simple copper (ii) hydroxide.
Jin X, et al.
Chemical Communications (Cambridge, England), 48(41), 4974-4976 (2012)
Sonja Kosuta et al.
Journal of environmental quality, 31(3), 910-916 (2002-05-25)
The City of Montreal, Canada, evaluated the environmental impact and usefulness of in-ground copper (Cu)-treated baskets in controlling root growth of hardwood trees in nursery culture. Using baskets planted with 5-yr-old Norway maple (Acer platanoides L.) trees, the amount and
E S Vasetskiĭ et al.
Izvestiia Akademii nauk SSSR. Seriia biologicheskaia, (1)(1), 148-151 (1989-01-01)
A specific cosedimentation of proteins and their complexes with DNA at low temperature (M-band technique) has been demonstrated. Model experiments with reconstituted SV40 DNA-topoisomerase I and SV40 DNA-E. coli RNA polymerase complexes demonstrated the potential and capacities of the method.
Mechanically stable, hierarchically porous Cu 3 (btc) 2 (HKUST-1) monoliths via direct conversion of copper (ii) hydroxide-based monoliths.
Moitra N, et al.
Chemical Communications (Cambridge, England), 51(17), 3511-3514 (2015)
Caroline K Nguyen et al.
Water research, 45(16), 5302-5312 (2011-08-27)
A rapid reaction between free chlorine and the cupric hydroxide [Cu(OH)2] solids commonly found on pipe walls in premise plumbing can convert free chlorine to chloride and rapidly age Cu(OH)2 to tenorite (CuO). This reaction has important practical implications for
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