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Key Documents

383058

Sigma-Aldrich

Zinc acetate dihydrate

ACS reagent, ≥98%

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About This Item

Linear Formula:
Zn(CH3COO)2 · 2H2O
CAS Number:
Molecular Weight:
219.51
Beilstein:
3732513
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NB.24

grade

ACS reagent

Quality Level

Assay

≥98%
98.0-101.0% (ACS specification)

form

powder, crystals or chunks

reaction suitability

reagent type: catalyst
core: zinc

impurities

≤0.005% insolubles

pH

6.0-7.0 (25 °C, 5%)

anion traces

chloride (Cl-): ≤5 ppm
sulfate (SO42-): ≤0.005%

cation traces

Ca: ≤0.005%
Fe: ≤5 ppm
K: ≤0.01%
Mg: ≤0.005%
Na: ≤0.05%
Pb: ≤0.002%

SMILES string

O.O.CC(=O)O[Zn]OC(C)=O

InChI

1S/2C2H4O2.2H2O.Zn/c2*1-2(3)4;;;/h2*1H3,(H,3,4);2*1H2;/q;;;;+2/p-2

InChI key

BEAZKUGSCHFXIQ-UHFFFAOYSA-L

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General description

Zinc acetate dehydrate is an organic zinc salt. Its enthalpy of formation has been studied using solution calorimetry. Its vibrational spectra has been analyzed. It decomposes into ZnO (zinc oxide) nanoparticles which has been investigated using time-of-flight secondary ion mass spectrometry (TOF-SIMS). A study on the crystalline structure has revealed that it is monoclinic with space group C2/c.

Application

Zinc acetate dehydrate was used as seeds to grow ZnO nanorods on the microfibers of PET (polyethylene terephthalate) fabric.
It may be used in the synthesis of layered Zn-arylphosphonates with potential application in sorption, ion exchange or catalysis. Also it may be used in the ultrasonic preparation of zinc sulfide nanoparticles coated on silica particles.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Development of superhydrophilic and superhydrophobic polyester fabric by growing Zinc Oxide nanorods.
Ashraf M, et al.
Journal of Colloid and Interface Science, 394, 545-553 (2013)
The crystal structure of zinc acetate dihydrate, Zn(CH3COO)2.2H2O.
Niekerk V, et al.
Acta Crystallographica, 6(8-9), 720-723 (1953)
Surface synthesis of zinc sulfide nanoparticles on silica microspheres: sonochemical preparation, characterization, and optical properties.
Dhas, N.A. et al.
Chemistry of Materials, 11(3), 806-813 (1999)
In situ thermo-TOF-SIMS study of thermal decomposition of zinc acetate dihydrate.
Ghule AV, et al.
Journal of Mass Spectrometry : Jms, 39(10), 1202-1208 (2004)
Vibrational spectra and structures of zinc carboxylates I. Zinc acetate dihydrate.
Ishioka T, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 54(12), 1827-1835 (1998)

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