164542

Ethyl 3-furoate

98%

• Empirical Formula (Hill Notation): C₇H₈O₃
• CAS Number: 614-98-2
• Molecular Weight: 140.14
• EC Number: 210-403-5
• MDL number: MFCD00005348
• UNSPSC Code: 12352100
• PubChem Substance ID: 24850082
• NACRES: NA.22

Properties

• Assay: 98%
• form: liquid
• refractive index: n20/D 1.46 (lit.)
• bp: 93-95 °C/35 mmHg (lit.)
• density: 1.038 g/mL at 25 °C (lit.)
• functional group: ester
• storage temp.: 2-8°C
• SMILES string: CCOC(=O)c1ccoc1
• InChI: 1S/C7H8O3/c1-2-10-7(8)6-3-4-9-5-6/h3-5H,2H2,1H3
• InChI key: LOFDXZJSDVCYAS-UHFFFAOYSA-N

Description

General description

Ethyl 3-furoate undergoes regioselective palladium(0)-catalyzed arylation reaction with aryl bromides.

Application

Ethyl 3-furoate was used as starting reagent for the synthesis of ethyl 2,3-bis(trifluoromethyl)-7-oxabicyclo[2,2,1]hepta-2,5-diene-5-carboxylate and 4-(1-hydroxy-1-methyl-ethyl)-furan-2-sulfonamide.

Safety Information

• Pictograms: GHS02
• Signal Word: Warning
• Hazard Statements: H226
• Precautionary Statements: P210 - P233 - P240 - P241 - P242 - P243
• Hazard Classifications: Flam. Liq. 3
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 138.2 °F - closed cup
• Flash Point(C): 59 °C - closed cup