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129046

Sigma-Aldrich

2,2,2-Trifluoroethylhydrazine solution

70 wt. % in H2O

Synonym(s):

Trifluoroethylhydrazine

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About This Item

Linear Formula:
CF3CH2NHNH2
CAS Number:
Molecular Weight:
114.07
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

concentration

70 wt. % in H2O

refractive index

n20/D 1.361

transition temp

flash point 62 °C

density

1.294 g/mL at 25 °C

functional group

amine
fluoro
hydrazine

SMILES string

NNCC(F)(F)F

InChI

1S/C2H5F3N2/c3-2(4,5)1-7-6/h7H,1,6H2

InChI key

OPMFFAOEPFATTG-UHFFFAOYSA-N

Application

2,2,2-trifluoroethylhydrazine was added to myoglobin to study its interaction with heme protein. It was also used to determine aldehydes and acetone simultaneously in water.
Building block for fluorinated pyridazines and fluoroalkyl hydrazones of β-phosphonates.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

143.6 °F

Flash Point(C)

62 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthetic Communications, 36, 2719-2719 (2006)
Hyun-Hee Lim et al.
Journal of chromatographic science, 55(2), 109-116 (2016-11-02)
As the popularity of body art including tattoo ink has increased, the safety associated with it has become an important interest. In this study, twenty volatile organic compounds (VOCs) and two aldehydes in tattoo inks were identified and quantified. Headspace
Journal of Fluorine Chemistry, 121, 177-177 (2003)
Y S Choe et al.
The Journal of biological chemistry, 266(13), 8523-8530 (1991-05-05)
The oxidative reaction of equine myoglobin with alkylhydrazines results primarily in introduction of the alkyl group at the sterically hindered gamma-meso position. The gamma-meso adducts formed with ethyl- and n-butylhydrazine have been isolated and unambiguously identified. With high pressure liquid
Karolina C Hernandes et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 36(12), 1808-1821 (2019-10-10)
Compounds with toxic potential may occur in beer, such as carbonyl compounds (acetaldehyde, acrolein, ethyl carbamate [EC] and formaldehyde) and furan derivatives [furfural and furfuryl alcohol (FA)]. The objective of this study was, for the first time, to validate a

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