Skip to Content
Merck
All Photos(2)

Documents

496839

Sigma-Aldrich

3-Buten-1-ol

96%

Synonym(s):

Allylcarbinol

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
CH2=CHCH2CH2OH
CAS Number:
Molecular Weight:
72.11
Beilstein:
1633504
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

96%

refractive index

n20/D 1.421 (lit.)

bp

112-114 °C (lit.)

density

0.838 g/mL at 25 °C (lit.)

SMILES string

OCCC=C

InChI

1S/C4H8O/c1-2-3-4-5/h2,5H,1,3-4H2

InChI key

ZSPTYLOMNJNZNG-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

3-Buten-1-ol is a homoallyl alcohol that can be prepared by the dehydration of 1,4-butanediol using cerium catalyst. The intramolecular hydrogen bonding of 3-buten-1-ol has been studied using FT-IR and 1H NMR spectroscopic data. Its microwave spectrum has been recorded and analyzed. The alkylation reaction of 3-buten-1-ol using titanium-organoaluminum system has been studied. Its gas-phase enthalpy of formation has been reported to be -147.3 ± 1.8kJ mol-1.

Application

Employed in a study of the Mn-catalyzed hydrohydrazination of olefins. Also used in a study of the conversion of propargylic acetates to ethers cataylzed by ferric chloride.

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

91.4 °F - closed cup

Flash Point(C)

33 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Transition metal promoted alkylations of unsaturated alcohols: the methylation and ethylation of 3-buten-1-ol using titanium tetrachloride-organoaluminum systems.
Youngblood AV, et al.
Journal of Organometallic Chemistry, 146(3), 221-228 (1978)
Synlett, 2278-2278 (2006)
The conformational composition of 3-buten-1-ol, the importance of intramolecular hydrogen bonding.
Bakke JM and Bjerkeseth LH.
Journal of Molecular Structure, 470(3), 247-263 (1998)
Jérôme Waser et al.
Journal of the American Chemical Society, 128(35), 11693-11712 (2006-08-31)
The discovery, study, and implementation of the Co- and Mn-catalyzed hydrohydrazination and hydroazidation reactions of olefins are reported. These reactions are equivalent to direct hydroaminations of C-C double bonds with protected hydrazines or hydrazoic acid but are based on a
Dehydration of 1,4-butanediol into 3-buten-1-ol catalyzed by ceria.
Sato S, et al.
Catalysis Communications, 5(8), 397-400 (2004)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service