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204870

Sigma-Aldrich

Ytterbium(III) chloride hexahydrate

99.998% trace metals basis

Synonym(s):

Ytterbium trichloride hydrate, Ytterbium(III) chloride·6hydrate

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About This Item

Linear Formula:
YbCl3 · 6H2O
CAS Number:
Molecular Weight:
387.49
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Assay

99.998% trace metals basis

form

powder and chunks

reaction suitability

reagent type: catalyst
core: ytterbium

impurities

≤25.0 ppm Trace Rare Earth Analysis

mp

180 °C (dec.) (lit.)

density

2.58 g/mL at 25 °C (lit.)

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Yb](Cl)Cl

InChI

1S/3ClH.6H2O.Yb/h3*1H;6*1H2;/q;;;;;;;;;+3/p-3

InChI key

LEYFXTUKPKKWMP-UHFFFAOYSA-K

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General description

Ytterbium(III) chloride hexahydrate is a white crystalline solid used as a precursor to synthesize nanomaterials and as acatalyst in various organic transformations.

Application

Ytterbium(III) chloride hexahydrate can be used as a precursor:
  • To synthesize ytterbium oxide nanodiscs to fabricate white LEDs.
  • To prepare NaYF4:Yb/Ho/Mn upconversion nanoparticles with good luminescent intensity, for biomedical applications.
  • To fabricate three-dimensional NaYF4:Yb3+/Tm3+hexagonal prisms for near IR photocatalytic H2 evolution.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Three-dimensional NaYF4:Yb3+/Tm3+ hexagonal prisms coupled with ZnIn2S4 nanosheets for boosting near-infrared photocatalytic H2 evolution
Zhouze Chen, et al.
Journal of Environmental Chemical Engineering, 10, 108352-108352 (2022)
Simple one pot synthesis of luminescent europium doped yttrium oxide Y2O3: Eu nanodiscs for phosphor converted warm white LEDs
Julian Petry, et al.
Nanoscale advances, 4, 858-864 (2022)
Enhancement of Luminescence Intensity in Red Emitting NaYF4:Yb/Ho/Mn Upconversion Nanophosphors by Variation of Reaction Parameters
Kumbam Lingeshwar Reddy, et al.
The Journal of Physical Chemistry C, 121, 11783-11793 (2017)
Uliana Kostiv et al.
Beilstein journal of nanotechnology, 6, 2290-2299 (2016-01-07)
NaYF4:Yb(3+)/Er(3+) nanoparticles were synthesized by thermal decomposition of lanthanide trifluoroacetates using oleylamine (OM) as both solvent and surface binding ligand. The effect of reaction temperature and time on the properties of the particles was investigated. The nanoparticles were characterized by

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