GF04978963
Rhodium
foil, not light tested, 10x10mm, thickness 0.012mm, as rolled, 99.9%
Synonym(s):
Rhodium, RH000205
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About This Item
Empirical Formula (Hill Notation):
Rh
CAS Number:
Molecular Weight:
102.91
MDL number:
UNSPSC Code:
12141738
PubChem Substance ID:
NACRES:
NA.23
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Assay
99.9%
form
foil
manufacturer/tradename
Goodfellow 049-789-63
resistivity
4.33 μΩ-cm, 20°C
size × thickness
10x10 mm × 0.012 mm
bp
3727 °C (lit.)
mp
1966 °C (lit.)
density
12.41 g/cm3 (lit.)
SMILES string
[Rh]
InChI
1S/Rh
InChI key
MHOVAHRLVXNVSD-UHFFFAOYSA-N
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General description
For updated SDS information please visit www.goodfellow.com.
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Product of Goodfellow
Storage Class Code
13 - Non Combustible Solids
WGK
nwg
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Huw M L Davies et al.
Chemical Society reviews, 40(4), 1857-1869 (2011-03-02)
This tutorial review presents a description of the controlling elements of intermolecular C-H functionalization by means of C-H insertion by donor/acceptor rhodium carbenes. These rhodium carbenes, readily derived from the combination of diazo compounds with dirhodium(ii) catalysts, are sufficiently reactive
Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms
Albert Padwa
Chemical Society reviews, 38(11), 3072-3081 (2009-10-23)
In this tutorial review, the rhodium(II)-catalyzed domino reactions of alpha-diazo carbonyl compounds are summarized. The article will emphasize some of the more recent synthetic applications of the rhodium carbenoid cyclization/cycloaddition domino cascade for alkaloid synthesis. The many structurally diverse and
Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.
Denise A Colby et al.
Chemical reviews, 110(2), 624-655 (2009-05-15)
Xing-Zhong Shu et al.
Chemical Society reviews, 41(23), 7698-7711 (2012-08-17)
Transition metal-catalyzed acyloxy migration of propargylic esters offers versatile entries to allene and vinyl carbene intermediates for various fascinating subsequent transformations. Most π-acidic metals (e.g. gold and platinum) are capable of facilitating these acyloxy migration events. However, very few of
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