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CRM42377

Supelco

Abamectin

certified reference material

Synonym(s):

Abamectin, Avermectin B1

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About This Item

CAS Number:
71751-41-2
MDL number:
MFCD01769550
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material

Quality Level

300

API family

abamectin

form

liquid

packaging

pkg of 100 mg

SMILES string

CCC(C)C1O[C@@]2(C[C@@H]3CC(C\C=C(C)\[C@@H](O[C@H]4C[C@H](OC)[C@@H](O[C@H]5C[C@H](OC)[C@@H](O)[C@H](C)O5)[C@H](C)O4)[C@@H](C)\C=C\C=C6/COC7[C@H](O)C(C)=CC(C(=O)O3)[C@]67O)O2)C=C[C@@H]1C

InChI

1S/C48H72O14/c1-11-25(2)43-28(5)17-18-47(62-43)23-34-20-33(61-47)16-15-27(4)42(26(3)13-12-14-32-24-55-45-40(49)29(6)19-35(46(51)58-34)48(32,45)52)59-39-22-37(54-10)44(31(8)57-39)60-38-21-36(53-9)41(50)30(7)56-38/h12-15,17-19,25-26,28,30-31,33-45,49-50,52H,11,16,20-24H2,1-10H3/b13-12+,27-15+,32-14+/t25-,26-,28-,30-,31-,33+,34-,35?,36-,37-,38-,39-,40+,41-,42-,43+,44-,45+,47+,48+/m0/s1

InChI key

RRZXIRBKKLTSOM-RDKIRRGNSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Abamectin is an insecticide, acaricide, and nematicide that belongs to the avermectins group of chemical compounds. Abamectin is a mixture two homologues containing >80% avermectin B1a and <20% avermectin B1b. It is used for the protection of ornamentals, cotton, citrus, pome fruit, nuts, vegetables, potatoes, and other crops against mites, leaf miners, suckers, colorado beetles, etc. It is commonly found in veterinary drugs due to its broad spectrum anti-parasitic activity.

Application

It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques.
The abamectin (CRM) can also be used to:
  • Study the toxicity of abamectin towards bacteria, algae, daphnids, and fishes
  • Examine the sorption and dissipation of abamectin in different soils
  • Determine abamectin and azadirachtin residues in orange samples using LC-ESI-MS
  • Develop a method to measure the amount of abamectin in citrus fruits
  • Determine abamectin in citrus fruits with SPE coupled with dispersive liquid-liquid microextraction and HPLC-UV detection
  • Measure abamectin and two other acaricide residues in green beans by extraction using QuEChERS method and further analysis by HPLC

Footnote

To see an example of a Certificate of Analysis for this material enter LRAC9228 in the Documents slot below. This is an example certificate only and may not be the lot that you receive.

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - STOT RE 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

>302.0 °F

Flash Point(C)

> 150 °C

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
LRAD3433
LRAC9228

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Mohammad Rezaee et al.
Journal of separation science, 36(16), 2629-2634 (2013-08-06)
A new pretreatment method, SPE combined with dispersive liquid-liquid microextraction, was proposed for the determination of abamectin in citrus fruit samples for the first time. In this method, fruit samples were extracted by ultrasound-assisted extraction followed by SPE. Then, the
A I Valenzuela et al.
Journal of chromatography. A, 871(1-2), 57-65 (2000-03-29)
Liquid chromatography coupled to electrospray mass spectrometry (LC-ES-MS) with positive ion detection was used to determine abamectin in oranges. MS conditions were optimized to achieve maximum sensitivity. The main ion for abamectin was [M+Na]+ at a fragmentor voltage of 180
Andreza Camilotti Dionisio et al.
Chemosphere, 151, 17-29 (2016-03-01)
Abamectin is a broad-spectrum antiparasitic agent that has been widely employed in veterinary medicine and has also been used as a pesticide in agriculture. Veterinary drugs may reach the soil and may be transported to surface and ground waters, posing
O J Pozo et al.
Journal of chromatography. A, 992(1-2), 133-140 (2003-05-09)
A rapid and sensitive LC-ESI-MS-MS method has been developed for the determination of azadirachtin and abamectin residues in orange samples. Samples were extracted with acetonitrile, in a high-speed blender. After the addition of sodium acetate, an aliquot of extract was
Mohamed E I Badawy et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 55(6), 517-524 (2020-02-18)
The current study estimated the dissipation rates of abamectin, chlorfenapyr and pyridaben acaricides in pods of green beans (Phaseolus vulgaris L.) under field conditions in Egypt. Pesticides were extracted and cleaned-up by QuEChERS method and were analyzed by HPLC. The
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