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T81000

Sigma-Aldrich

Trioctylamine

98%

Synonym(s):

TOA

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About This Item

Linear Formula:
[CH3(CH2)7]3N
CAS Number:
1116-76-3
Molecular Weight:
353.67
Beilstein:
1210618
EC Number:
214-242-1
MDL number:
MFCD00009560
UNSPSC Code:
12352100
PubChem Substance ID:
24900500
NACRES:
NA.22

Quality Level

200

Assay

98%

refractive index

n20/D 1.449 (lit.)

bp

164-168 °C/0.7 mmHg (lit.)
365-367 °C (lit.)

density

0.809 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCN(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51N/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

XTAZYLNFDRKIHJ-UHFFFAOYSA-N

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Application

Trioctylamine is used as an extractant for organic acids (such as TCA, succinic acid, and acetic acid), and precious metals.

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1 Oral

Target Organs

Heart

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

334.4 °F - closed cup

Flash Point(C)

168 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL6401
WXBF2288V
0000191488
0000208482
0000220104

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M L Puttemans et al.
Journal - Association of Official Analytical Chemists, 66(4), 1039-1044 (1983-07-01)
Dyes are determined in gelatin-containing sweets. The gelatin must be eliminated first because it interferes with the normal ion-pair extraction of dyes with tri-n-octylamine to chloroform. Techniques such as precipitation of gelatin with organic solvents, and acid and enzymatic digestion
Chu-Hsun Lu et al.
Biotechnology and bioengineering, 79(2), 200-210 (2002-07-13)
Lipases immobilized on polypropylene powders have been used as the biocatalyst in the enantioselective hydrolysis of (S)-naproxen from racemic naproxen thioesters in isooctane, in which trioctylamine was added to perform in situ racemization of the remaining (R)-thioester substrate. A detailed
Evgenii S Stoyanov et al.
Journal of the American Chemical Society, 128(26), 8500-8508 (2006-06-29)
The N-H stretching frequencies of tri-n-octylammonium salts are reported for a series of weakly basic anions (A(-)), many of which are the conjugate bases of known strong acids and superacids. Data have been collected primarily in carbon tetrachloride, where Oct(3)N(+)-H...A(-)
Yun Suk Huh et al.
Biotechnology letters, 26(20), 1581-1584 (2004-12-18)
Acetic acid is by-product from fermentation processes for producing succinic acid using Mannheimia succiniciproducens . To obtain pure succinic acid from the final fermentation broth, acetic acid was selectively removed based on the different extractability of succinic acid and acetic
C N Lin et al.
Biotechnology and bioengineering, 69(1), 31-38 (2000-05-23)
A lipase-catalyzed enantioselective hydrolysis process under conditions of continuous in situ racemization of substrate with trioctylamine as the catalyst was developed for the production of (S)-suprofen from (R,S)-suprofen 2,2,2-trifluoroethyl thioester in isooctane. A detailed investigation of trioctylamine concentration on the
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