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908444

Sigma-Aldrich

DPZ

95%

Synonym(s):

5,6-Bis(5-methoxythiophen-2-yl)pyrazine-2,3-dicarbonitrile

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About This Item

Empirical Formula (Hill Notation):
C16H10N4O2S2
CAS Number:
1818245-74-7
Molecular Weight:
354.41
UNSPSC Code:
12352101
NACRES:
NA.22

Assay

95%

form

(Powder or Solid or Chunks)

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

storage temp.

2-8°C

Related Categories

Application

DPZ is an organic photoredox catalyst used in a variety of visible-light mediated transformations including in asymmetric dual catalytic systems.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Organocatalytic Enantioselective Addition of α-Aminoalkyl Radicals to Isoquinolines

Controllable Chemoselectivity in Visible-Light Photoredox Catalysis: Four Diverse Aerobic Radical Cascade Reactions

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Yanli Yin et al.
Journal of the American Chemical Society, 140(19), 6083-6087 (2018-04-11)
An enantioselective protonation strategy has been successfully applied to the synthesis of chiral α-tertiary azaarenes. With a dual catalytic system involving a chiral phosphoric acid and a dicyanopyrazine-derived chromophore (DPZ) photosensitizer that is mediated by visible light, a variety of
Xinfei Liu et al.
Angewandte Chemie (International ed. in English), 54(39), 11443-11447 (2015-07-28)
Reported is the controllable selectivity syntheses of four distinct products from the same starting materials by visible-light photoredox catalysis. By employing a dicyanopyrazine-derived chromophore (DPZ) as photoredox catalyst, an aerobic radical mechanism has been developed, and allows the reactions of
Xiangyuan Liu et al.
Organic letters, 20(19), 6298-6301 (2018-09-27)
With a dual organocatalytic system involving a chiral phosphoric acid and a dicyanopyrazine-derived chromophore (DPZ) photosensitizer and under the irradiation with visible light, an enantioselective Minisci-type addition of α-amino acid-derived redox-active esters (RAEs) to isoquinolines has been developed. A variety

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