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717398

Sigma-Aldrich

(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

97%

Synonym(s):

(Sp)-1-(Diphenylphosphino)-2-[(4S)-4-isopropyl-2-oxazolyl]ferrocene

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About This Item

Empirical Formula (Hill Notation):
C28H28FeNOP
CAS Number:
163169-29-7
Molecular Weight:
481.35
MDL number:
MFCD15144869
UNSPSC Code:
12352005
PubChem Substance ID:
329763485
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

optical activity

[α]20/D 366°, c = 0.1 in chloroform

mp

158-162 °C

functional group

ether
phosphine

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CC(C)[C@H]2COC(=N2)[C]3[CH][CH][CH][C]3P(c4ccccc4)c5ccccc5

InChI

1S/C23H23NOP.C5H5.Fe/c1-17(2)21-16-25-23(24-21)20-14-9-15-22(20)26(18-10-5-3-6-11-18)19-12-7-4-8-13-19;1-2-4-5-3-1;/h3-15,17,21H,16H2,1-2H3;1-5H;/t21-;;/m1../s1

InChI key

FELCHLOAEMNOQM-GHVWMZMZSA-N

Related Categories

Application

(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline can be used as a chiral ligand in the synthesis of rhodium, iridium, ruthenium, and osmium metal complexes.

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL8817
MKCM0843
MKCL1721
MKBC5380

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Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino) ferrocenyl]-4-isopropyloxazoline
Carmona D, et al.
Journal of Organometallic Chemistry, 691(26), 5560-5566 (2006)
Octahedral ruthenium (II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino) ferrocenyl]-4-(isopropyl) oxazoline (FcPN). X-Ray crystal structures of fac-[RuCl2 (PMe3) 2 (FcPN)] and fac-[RuCl2 (dppm)(FcPN)](dppm= bis (diphenylphosphino)methane)
Gimeno J, et al.
Journal of Organometallic Chemistry, 637, 463-468 (2001)

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