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703516

Sigma-Aldrich

Zinc chloride solution

greener alternative

1.9 M in 2-methyltetrahydrofuran

Synonym(s):

Dichlorozinc

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About This Item

Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
MDL number:
MFCD00011295
UNSPSC Code:
12352302
PubChem Substance ID:
329762045
NACRES:
NA.23

form

liquid

Quality Level

100

reaction suitability

reagent type: catalyst
core: zinc

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

concentration

1.9 M in 2-methyltetrahydrofuran
25 % (w/w)

density

1.07 g/mL at 25 °C

greener alternative category

, Aligned

SMILES string

Cl[Zn]Cl

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Lewis acid in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Signal Word

Danger

Hazard Statements

H225,H302,H314,H335,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

10.4 °F - closed cup - Solvent

Flash Point(C)

-12 °C - closed cup - Solvent

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR7617
SHBS2984
SHBQ6222
SHBP7422
SHBN9204

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Zinc chloride anhydrous, free-flowing, Redi-Dri™, ACS reagent, ≥97%

Sigma-Aldrich

746355

Zinc chloride

Zinc chloride anhydrous, free-flowing, Redi-Dri™, reagent grade, ≥98%

Sigma-Aldrich

793523

Zinc chloride

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Rat pancreatic islet cell apoptosis is minimal after prolonged culture in 10 mmol/l glucose (G10), largely increased in 5 mmol/l glucose (G5) and moderately increased in 30 mmol/l glucose (G30). This glucose-dependent asymmetric V-shaped profile is preceded by parallel changes
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Journal of the American Chemical Society, 134(36), 14690-14693 (2012-08-22)
Reactions of ZrCl(4) and single or mixed linear dicarboxylic acids bearing methyl or azide groups lead to highly stable isoreticular metal-organic frameworks (MOFs) with content-tunable, accessible, reactive azide groups inside the large pores. These Zr-based MOFs offer an ideal platform
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