597910

(4-Chlorophenyl)triethoxysilane

97%

• Synonym(s): 1-Chloro-4-triethoxysilylbenzene
• Linear Formula: ClC₆H₄Si(OC₂H₅)₃
• CAS Number: 21700-74-3
• Molecular Weight: 274.82
• EC Number: 244-533-9
• MDL number: MFCD00053217
• UNSPSC Code: 12352103
• PubChem Substance ID: 24881725
• NACRES: NA.22

Properties

• Assay: 97%
• refractive index: n20/D 1.474 (lit.)
• bp: 82-84 °C/0.07 mmHg (lit.)
• density: 1.069 g/mL at 25 °C (lit.)
• functional group: chloro
• SMILES string: CCO[Si](OCC)(OCC)c1ccc(Cl)cc1
• InChI: 1S/C12H19ClO3Si/c1-4-14-17(15-5-2,16-6-3)12-9-7-11(13)8-10-12/h7-10H,4-6H2,1-3H3
• InChI key: AFILDYMJSTXBAR-UHFFFAOYSA-N

Description

Application

(4-Chlorophenyl)triethoxysilane can be used:

• To facilitate the connection between dipolar mixed monolayers and zinc oxide in photovoltaic devices.
• As a substrate in the Ni-catalyzed decarboxylative coupling with alkynyl carboxylic acids to yield substituted diarylalkynes.
• As a substrate in the Hiyama cross-coupling reactions with 3-iodoazetidines to yield substituted 3-arylazetidines.
• As an intermediate in the synthesis of tripod-shaped oligo(p-phenylene)s, which are used in the surface immobilization of gold and CdS quantum dots for sensor applications.

Safety Information

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): >230.0 °F - closed cup
• Flash Point(C): > 110 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves