Skip to Content
Merck
All Photos(3)

Key Documents

481548

Sigma-Aldrich

Lithium trifluoromethanesulfonate

greener alternative

99.995% trace metals basis

Synonym(s):

LiTf, Lithium triflate, Trifluoromethanesulfonic acid lithium salt

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
CF3SO3Li
CAS Number:
Molecular Weight:
156.01
Beilstein:
4301818
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.995% trace metals basis

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤60 ppm Trace Metal Analysis

mp

>300 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

[Li+].[O-]S(=O)(=O)C(F)(F)F

InChI

1S/CHF3O3S.Li/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

InChI key

MCVFFRWZNYZUIJ-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

General description

Lithium trifluoromethanesulfonate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiOTf can be used for a variety of applications such as:
  • a polymeric layer for light-emitting electrochemical cells
  • an electrolyte for lithium-ion batteries
  • a recyclable catalyst for acetylation of alcohols and diacetylation of aldehydes
  • a separator for supercapacitors

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

An improved high-performance lithium-air battery
Jung H, et al.
Nature Chemistry, 4(7), 579-579 (2012)
Polymer light-emitting electrochemical cells: Doping, luminescence, and mobility
Edman L, et al.
Physical Review. B, Condensed Matter and Materials Physics, 70(11), 115212-115212 (2004)
Hu, Q.; Osswald, S.; Daniel, R.; Zhu, Y.; Wesel, S.; Ortiz, L.; Sadoway, D.R.
Journal of Power Sources, 196, 5604-5604 (2011)
Lithium trifluoromethanesulfonate (LiOTf) as a recyclable catalyst for highly efficient acetylation of alcohols and diacetylation of aldehydes under mild and neutral reaction conditions
Karimi B and Maleki J
The Journal of Organic Chemistry, 68(12), 4951-4954 (2003)
Development of all-solid-state mediator-enhanced supercapacitors with polyvinylidene fluoride/lithium trifluoromethanesulfonate separators
Zhou J, et al.
Journal of Power Sources, 196(23), 10479-10483 (2011)

Articles

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

See All

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service