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467871

Sigma-Aldrich

Sodium thiocyanate

≥99.99% trace metals basis

Synonym(s):

Sodium isothiocyanate, Sodium rhodanate, Sodium rhodanide, Sodium sulfocyanate

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About This Item

Linear Formula:
NaSCN
CAS Number:
Molecular Weight:
81.07
Beilstein:
3594965
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥99.99% trace metals basis

impurities

≤0.005% insolubles
≤0.2% Na2CO3
<100 ppm total metallic impurities

mp

287 °C (dec.) (lit.)

anion traces

S2-: ≤0.001%
chloride (Cl-): ≤0.01%
sulfate (SO42-): ≤0.01%

cation traces

Fe: ≤2 ppm
NH4+: ≤0.002%
heavy metals: ≤5 ppm

SMILES string

[Na]SC#N

InChI

1S/CHNS.Na/c2-1-3;/h3H;/q;+1/p-1

InChI key

VGTPCRGMBIAPIM-UHFFFAOYSA-M

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General description

Morphological and differential thermal analysis of complexes of sodium thiocyanate with poly(ethylene oxide) have been studied. Ionic deep eutectic solvents composed of acetamide+lithium nitrate/sodium thiocyanate have been investigated by dielectric relaxation spectroscopy.

Application

Sodium thiocyanate may be used as a reducing agent in the preparation of monodisperse gold oligoclusters.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1

Supplementary Hazards

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Satya N Tripathy et al.
The Journal of chemical physics, 142(18), 184504-184504 (2015-05-17)
A detailed investigation on the molecular dynamics of ionic deep eutectic solvents (acetamide + lithium nitrate/sodium thiocyanate) is reported. The study was carried out employing dielectric relaxation spectroscopy covering seven decades in frequency (10(-1)-10(6) Hz) and in a wide temperature
A Simple Method for the Size Controlled Synthesis of Stable Oligomeric Clusters of Gold Nanoparticles under Ambient Conditions.
Lawrence M, et al.
Journal of Visualized Experiments, 108, e53388-e53388 (2016)
Morphology and ionic conductivity of complexes of sodium iodide and sodium thiocyanate with poly (ethylene oxide).
Lee CC and Wright PV.
Polymer, 23(5), 681-689 (1982)
Nancy E Breen et al.
PeerJ, 7, e6644-e6644 (2019-04-12)
The illegal practice of using cyanide (CN) as a stunning agent to collect fish for both the marine aquarium and live fish food trades has been used throughout the Indo-Pacific for over 50 years. CN fishing is destructive to all
Vincent Ball et al.
Langmuir : the ACS journal of surfaces and colloids, 21(9), 4129-4137 (2005-04-20)
In this study, we investigate the buildup of PEI-(PSS-PAH)(n) polyelectrolyte multilayers at pH 7.4 in the presence of either NaCl or NaSCN as a supporting electrolyte. It appears that in the presence of increasing thiocyanate concentrations (from 0.1 to 0.5

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