464635
Trifluoromethanesulfonimide
≥95.0% (19F-NMR)
Synonym(s):
Bis(trifluoromethanesulfonyl)amine
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About This Item
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Quality Level
Assay
≥95.0% (19F-NMR)
form
solid
bp
90-91 °C (lit.)
mp
46-57 °C (lit.)
SMILES string
FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F
InChI
1S/C2HF6NO4S2/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h9H
InChI key
ZXMGHDIOOHOAAE-UHFFFAOYSA-N
Related Categories
General description
Trifluoromethanesulfonimide is a promising Bronsted acid catalyst and is superior to scandium triflate in catalytic action.
Application
Trifluoromethanesulfonimide may be used as a catalyst for the preparation of 1-substituted-1H-1,2,3,4-tetrazoles.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1
Storage Class Code
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Trifluoromethanesulfonimide catalysed synthesis of 1-substituted-1H-1, 2, 3, 4-tetrazoles using glycerol as green solvent at room temperature.
J. Chem. Res. (M), 40(9), 570-572 (2016)
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The exciton-dominated light emission of two-dimensional (2D) semiconductors is determined largely by the doping state and the formation of defects. Extensive studies have shown that chemical treatment critically modifies the doping state and defect state of chemical vapor deposition (CVD)-grown
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