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414670

Sigma-Aldrich

1-Iodo-2-(trimethylsilyl)acetylene

97%

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About This Item

Linear Formula:
(CH3)3SiC≡CI
CAS Number:
18163-47-8
Molecular Weight:
224.11
MDL number:
MFCD00274201
UNSPSC Code:
12352100
PubChem Substance ID:
24865951
NACRES:
NA.22

Assay

97%

form

liquid

refractive index

n20/D 1.511 (lit.)

bp

130 °C (lit.)

density

1.46 g/mL at 25 °C (lit.)

functional group

iodo

storage temp.

2-8°C

SMILES string

C[Si](C)(C)C#CI

InChI

1S/C5H9ISi/c1-7(2,3)5-4-6/h1-3H3

InChI key

HNIRHTRSZDSMOF-UHFFFAOYSA-N

Application

1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

118.4 °F - closed cup

Flash Point(C)

48 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBV8893V
MKBR6193V
09505HH
13023EQ
U14312

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Elodie E Marlier et al.
Inorganic chemistry, 51(4), 2079-2085 (2012-02-11)
A model for cobalamin was synthesized using a new monoanionic tetradentate nitrogen donor ligand; 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine (Tol-BDI((2-pp)2)H) (1), which utilizes isopropylpyridines as pendant arms on a β-diketiminate (BDI) backbone. During the synthesis of 1, the rearrangement product, Tol-BDI((2-pp)(4-pp))H (2) was observed.
Novel polyacetylenes containing pendant 1-pyrenyl groups: synthesis, characterization, and thermal and optical properties.
Rivera E, et al.
Polymer, 43(19), 5059-5068 (2009)

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