407801
6-Methyl-1,3,5-triazine-2,4-diamine
98%
Synonym(s):
2,4-Diamino-6-methyl-1,3,5-triazine, Acetoguanamine
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About This Item
Empirical Formula (Hill Notation):
C4H7N5
CAS Number:
Molecular Weight:
125.13
Beilstein:
118348
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
powder
mp
274-276 °C (lit.)
SMILES string
Cc1nc(N)nc(N)n1
InChI
1S/C4H7N5/c1-2-7-3(5)9-4(6)8-2/h1H3,(H4,5,6,7,8,9)
InChI key
NJYZCEFQAIUHSD-UHFFFAOYSA-N
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General description
6-Methyl-1,3,5-triazine-2,4-diamine butane-1,4-diol monosolvate crystallizes with 6-methyl-1,3,5-triazine-2,4-diamine (DMT) and a molecule of butane-1,4-diol in the asymmetric unit. The DMT molecules form ribbons having centrosymmetric dimer motifs between DMT molecules along the c-axis. DMT and thymine forms a new metastable bicomponent hydrogel, which cage a number of organic solvents.
Application
6-Methyl-1,3,5-triazine-2,4-diamine may be used in the synthesis of s-Bodipy-triazine (BODIPY = 4,4-difluoro-4-borata-3a-azonia-4a-aza-s-indacene). It is a symmetric fluorescent sensor for Cu2+.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A symmetric and selective fluorescent Cu (II) sensor based on bodipy and s-triazine.
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Journal of Luminescence, 149, 215-220 (2014)
Metastability in a bi-component hydrogel of thymine and 6-methyl-1, 3, 5-triazine-2, 4-diamine: ultrasound induced vs. thermo gelation.
Roy B, et al.
Soft Matter, 8(8), 2366-2369 (2012)
Rajni M Bhardwaj et al.
Acta crystallographica. Section E, Structure reports online, 68(Pt 12), o3377-o3377 (2013-03-12)
The title co-crystal, C4H7N5·C4H10O2, crystallizes with one mol-ecule of 6-methyl-1,3,5-triazine-2,4-diamine (DMT) and one mol-ecule of butane-1,4-diol in the asymmetric unit. The DMT mol-ecules form ribbons involving centrosymmetric R2(2)(8) dimer motifs between DMT mol-ecules along the c-axis direction. These ribbons are
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