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403733

Sigma-Aldrich

1,3-Dichloropropene

90%, technical grade

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About This Item

Linear Formula:
ClCH2CH=CHCl
CAS Number:
542-75-6
Molecular Weight:
110.97
Beilstein:
1719556
EC Number:
208-826-5
MDL number:
MFCD00000985
UNSPSC Code:
12352100
PubChem Substance ID:
24865216
NACRES:
NA.22

grade

technical grade

Assay

90%

form

liquid

refractive index

n20/D 1.472 (lit.)

bp

97-112 °C (lit.)

density

1.198 g/mL at 25 °C (lit.)

functional group

chloro

SMILES string

ClC\C=C/Cl

InChI

1S/C3H4Cl2/c4-2-1-3-5/h1-2H,3H2/b2-1+

InChI key

UOORRWUZONOOLO-OWOJBTEDSA-N

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General description

1,3-Dichloropropene (1,3-D) is a clear, light-straw colored liquid. It is a soil fumigant useful for preplanting control of parasitic nematodes. Co-formulations of 1,3-D and chloropicrin are widely employed for preplant fumigation in the production of high-value crops.

Application

1,3-Dichloropropene may be employed in commercial fumigant preparations. It is used as pesticide in a study to investigate the photocatalytic degradation of water-soluble pesticides (cymoxanil, methomyl, oxamyl, dimethoate, pyrimethanil and telone) at pilot-plant scale.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

82.4 °F - closed cup

Flash Point(C)

28 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCK6189
MKCF4647
MKBZ0571V
13201CD
13103MR

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1, 3-Dichloropropene.
Yang RSH.
Residue Reviews, 19-35 (1986)
James E Klaunig et al.
Toxicological sciences : an official journal of the Society of Toxicology, 143(1), 6-15 (2014-10-31)
1,3-Dichloropropene (1,3-D) is a soil fumigant used primarily for preplanting control of parasitic nematodes. In a previous chronic dietary exposure study, 1,3-D induced an increased incidence of hepatocellular adenomas in male rats at a dose of 25 mg/kg/day. Although the mechanism
Daniel J Ashworth et al.
Journal of agricultural and food chemistry, 63(2), 415-421 (2014-12-23)
Co-formulations of 1,3-dichloropropene (1,3-D) and chloropicrin (CP) are commonly used for preplant fumigation in the production of high-value crops. Various ratios of 1,3-D to CP are available in these co-formulations. Collation of previous field data suggested that when the two
I Oller et al.
Journal of hazardous materials, 138(3), 507-517 (2006-07-15)
The technical feasibility and performance of photocatalytic degradation of six water-soluble pesticides (cymoxanil, methomyl, oxamyl, dimethoate, pyrimethanil and telone) have been studied at pilot-plant scale in two well-defined systems which are of special interest because natural solar UV light can
Amit J Jhala et al.
Pest management science, 68(2), 225-230 (2011-07-29)
Preplant fumigation with methyl bromide (MeBr) has been used for control of soilborne pests in high-value annual, perennial and nursery crops, but is being phased out. In 2007 and 2008, research trials were conducted to evaluate the effects of surface
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