384127
Diphenyl ditelluride
98%
Synonym(s):
Phenyl ditelluride
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About This Item
Linear Formula:
(C6H5)2Te2
CAS Number:
Molecular Weight:
409.41
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
powder
mp
65-67 °C (lit.)
SMILES string
[Te]([Te]c1ccccc1)c2ccccc2
InChI
1S/C12H10Te2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H
InChI key
VRLFOXMNTSYGMX-UHFFFAOYSA-N
Related Categories
General description
Diphenyl ditelluride (PhTe)2 is a versatile reagent used in the organic synthesis. Neurotoxicity by (PhTe)2 depends on the modulation of signaling pathways initiated at the plasma membrane. Comparative toxicological effects of diphenyl diselenide and (PhTe)2 in mice after in vivo administration has been reported. Teratogenic effects of (PhTe)2 on chicken embryo development has been investigated. The oxidative addition of (PhTe)2 to [Pd(PPh3)4] in dichloromethane is reported to yield [Pd6Cl2Te4(TePh)2(PPh3)6]·1/2CH2Cl2.
Application
Diphenyl ditelluride may be used in the assay of organolithium and Grignard reagents.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Daiane Francine Meinerz et al.
PeerJ, 2, e290-e290 (2014-04-09)
Organoselenium compounds have been pointed out as therapeutic agents. In contrast, the potential therapeutic aspects of tellurides have not yet been demonstrated. The present study evaluated the comparative toxicological effects of diphenyl diselenide (PhSe)2 and diphenyl ditelluride (PhTe)2 in mice
Robert B Cody et al.
Journal of the American Society for Mass Spectrometry, 30(7), 1321-1324 (2019-05-08)
Elemental compositions are commonly determined from the exact m/z of the monoisotopic peak, which is often the lightest isotope. However, the lightest isotope peak is often weak or absent and the monoisotopic peak can be difficult to identify for organometallics
Regina Pessoa-Pureur et al.
Oxidative medicine and cellular longevity, 2014, 458601-458601 (2014-07-23)
Evidence from our group supports that diphenyl ditelluride (PhTe)2 neurotoxicity depends on modulation of signaling pathways initiated at the plasma membrane. The (PhTe)2-evoked signal is transduced downstream of voltage-dependent Ca(2+) channels (VDCC), N-methyl-D-aspartate receptors (NMDA), or metabotropic glutamate receptors activation
The oxidative addition of diphenyl diselenide and ditelluride to tetrakis (triphenylphosphine) palladium.
Oilunkaniemi R, et al.
Journal of Organometallic Chemistry, 623(1), 168-175 (2001)
The Journal of Organic Chemistry, 54, 5627-5627 (1989)
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