383317
Zinc acetate
99.99% trace metals basis
Synonym(s):
Zn(OAc)2
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About This Item
Linear Formula:
(CH3CO2)2Zn
CAS Number:
Molecular Weight:
183.48
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99.99% trace metals basis
form
solid
reaction suitability
core: zinc
reagent type: catalyst
impurities
<0.2% water
density
1.84 g/mL at 25 °C (lit.)
SMILES string
CC(O[Zn]OC(C)=O)=O
InChI
1S/2C2H4O2.Zn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
InChI key
DJWUNCQRNNEAKC-UHFFFAOYSA-L
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General description
Zinc acetate is primarily utilized as a precursor or catalyst in various synthetic reactions. In organic chemistry, zinc acetate finds application as a reagent in the formation of carbon-carbon bonds. It can facilitate the synthesis of esters, allylic alcohols, and acetals. For example, it can promote the acylation of alcohols, phenols, and amines to form esters, such as the Fischer esterification reaction. Zinc acetate has also been used in the synthesis of metal-organic frameworks (MOFs). MOFs are porous materials consisting of metal ions or clusters coordinated to organic ligands. Zinc acetate can act as a precursor for the formation of MOFs due to its ability to coordinate with organic linkers and form robust networks.
For small scale and high throughput uses, product is also available as ChemBeads (927805)
For small scale and high throughput uses, product is also available as ChemBeads (927805)
Application
Zinc acetate has been used in:
- Synthesis of layered Zn-arylphosphonates with potential application in sorption, ion exchange or catalysis.
- Ultrasonic preparation of zinc sulfide nanoparticles coated on silica particles.
- Synthesis of ZnO/ZnS composites throughion exchange method (1)
- Fabrication of 3D hierarchical ZnO/ZnSheterojunction branched nanowires for enhanced photoelectrochemical watersplitting (2)
- Synthesis of Co3O4-decorated ZnO@ZnS core-shellstructures for efficient photocatalytic overall water splitting (3)
- Synthesis of ZnO photocatalysts (4)
Preparation Note
Preparation of ZnSe nanostructures upon thermolysis of zinc acetate and selenourea in a mixture of octadecylamine and trioctylphosphine oxide.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Asit Baran Panda et al.
Langmuir : the ACS journal of surfaces and colloids, 23(2), 765-770 (2007-01-11)
Shape-, size-, and phase-controlled ZnSe nanostructures were synthesized by thermolysis of zinc acetate and selenourea using liganding solvents of octadecylamine (ODA) and trioctylphosphineoxide (TOPO) at different molar ratios. Materials synthesized in pure ODA resulted in uniform ultranarrow nanorods and nanowires
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