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Key Documents

377171

Sigma-Aldrich

1,2-Epoxyhexane

97%

Synonym(s):

1-Hexene oxide, Butyloxirane

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About This Item

Empirical Formula (Hill Notation):
C6H12O
CAS Number:
Molecular Weight:
100.16
Beilstein:
102568
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

97%

form

liquid

impurities

<3% acetic acid

refractive index

n20/D 1.406 (lit.)

bp

118-120 °C (lit.)

density

0.831 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCCCC1CO1

InChI

1S/C6H12O/c1-2-3-4-6-5-7-6/h6H,2-5H2,1H3

InChI key

WHNBDXQTMPYBAT-UHFFFAOYSA-N

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Application

  • Poly (epichlorohydrin-co-1, 2-epoxyhexane)–a promising precursor for an energetic azido polymer for cast-cure: Discusses the synthesis of a copolymer using epichlorohydrin and 1,2-epoxyhexane, aiming to develop an internal plasticizer for energetic applications (TM Klapötke, 2016).
  • Synthesis of hierarchically porous zeolite TS-1 with small crystal size and its performance of 1-hexene epoxidation reaction: This study investigates the catalytic performance of 1,2-epoxyhexane in the preparation of intermediates for various chemical industries (M Zhang et al., 2021).
  • Bioproduction of Chiral Epoxyalkanes using Styrene Monooxygenase from Rhodococcus sp. ST‐10 (RhSMO): Focuses on the enzymatic production of (S)-1,2-epoxyhexane using a biocatalyst, highlighting its potential in creating chiral epoxyalkanes (H Toda et al., 2014).
  • Silica islands regulated external Ti‐site environment of TS‐1 for enhanced performance of 1‐hexene epoxidation: Explores the use of modified TS-1 catalysts to improve the selectivity and performance of 1,2-epoxyhexane in epoxidation reactions (J Yuan et al., 2023).
  • Gas-phase Photocatalytic Oxidation of 1-Hexene Using Heterogeneous Semiconductor Materials: Describes the synthesis of 1,2-epoxyhexane through gas-phase photocatalytic oxidation, focusing on the selectivity and efficiency of the process (EA Kamba et al., 2023).

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

59.0 °F - closed cup

Flash Point(C)

15 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Ijaz Gul et al.
Journal of biotechnology, 311, 19-24 (2020-02-19)
Halohydrin dehalogenases (HHDHs) are valuable biocatalysts involved in the synthesis of β-substituted alcohols via their nucleophile-mediated ring-opening activity. To use directed evolution to unleash the latent potential of HHDHs for the synthesis of β-substituted alcohols, we report a high-throughput assay
W J Choi et al.
Applied microbiology and biotechnology, 54(5), 641-646 (2000-12-29)
A two-phase membrane bioreactor was developed to continuously produce enantiopure epoxides using the epoxide hydrolase activity of Rhodotorula glutinis. An aqueous/organic cascade, hydrophilic, hollow-fiber membrane bioreactor was used: (1) to carry out large-scale resolution of epoxides, (2) to continuously extract
Allison C Vander Wall et al.
Environmental science. Processes & impacts, 22(1), 66-83 (2019-11-02)
Secondary organic aerosol (SOA) particles are ubiquitous in air and understanding the mechanism by which they grow is critical for predicting their effects on visibility and climate. The uptake of three organic nitrates into semi-solid SOA particles formed by α-pinene
Thomas Klein et al.
Dalton transactions (Cambridge, England : 2003), 49(28), 9820-9834 (2020-07-08)
Al nanoparticles represent one of the most challenging classes of metal nanoparticles in synthesis and handling due to their high chemical reactivity and their affinity to oxidation. A promising wet chemical preparation route is the catalytic decomposition of alane adducts.
Zhimin Xue et al.
Chemistry, an Asian journal, 12(17), 2271-2277 (2017-06-20)
Development of inexpensive, easily prepared, non-toxic, and efficient catalysts for the cycloaddition of CO

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