Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

340332

Sigma-Aldrich

(S)-(+)-2-Heptanol

98%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
CH3(CH2)4CH(OH)CH3
CAS Number:
6033-23-4
Molecular Weight:
116.20
MDL number:
MFCD00065003
UNSPSC Code:
12352001
PubChem Substance ID:
24860798
NACRES:
NA.22

vapor density

4 (vs air)

Quality Level

100

vapor pressure

1 mmHg ( 15 °C)

Assay

98%

form

liquid

optical activity

[α]24/D +10°, neat

optical purity

ee: 97% (GLC)

refractive index

n20/D 1.421 (lit.)

bp

149-150 °C (lit.)

density

0.815 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

CCCCC[C@H](C)O

InChI

1S/C7H16O/c1-3-4-5-6-7(2)8/h7-8H,3-6H2,1-2H3/t7-/m0/s1

InChI key

CETWDUZRCINIHU-ZETCQYMHSA-N

Application

(S)-(+)-2-Heptanol can be used as a starting material to synthesize:
  •  (S)-(+)-2-benzoyloxyheptane by treating with benzoyl anhydride and Et3N in the presence of DMAP.       
  • (S)-2-(p-toluenesulfonyl)heptane by reacting with p-toluenesulfonyl chloride.      
  •   (+)-2-Heptyl acetate by treating with acetyl chloride.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

147.2 °F - closed cup

Flash Point(C)

64 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCW1861
MKCS6359
MKCS6360
MKCB6992
MKBX8597V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Christiane Kiske et al.
Journal of agricultural and food chemistry, 64(45), 8563-8571 (2016-11-04)
The absolute configurations of chiral β-mercaptoalkanones were previously assigned on the basis of the 1H NMR anisotropy method using (S)-2-methoxy-2-(1-naphthyl)propionic acid ((S)-MαNP) as the chiral auxiliary. This study presents a reinvestigation of the configurations of 4-mercapto-2-pentanone 1, 4-mercapto-2-heptanone 2, and
Enantioselective multidimensional gas chromatography of some secondary alcohols and their acetates from banana
Schubert, V, et al.
Zeitschrift fur Naturforschung B, 46(1-2), 33-36 (1991)
A study on the stereochemistry of direct conversion of polyamides to hydroxyesters using monomeric secondary chiral amines as a model compound
Kamimura A, et al.
Polymer Degradation and Stability, 160, 162-167 (2019)

Articles

Chiral Alcohols

Chiral Alcohols

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service