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Key Documents

206105

Sigma-Aldrich

Ammonium tetrachloroplatinate(II)

99%

Synonym(s):

Platinum(II)-ammonium chloride

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About This Item

Linear Formula:
(NH4)2PtCl4
CAS Number:
Molecular Weight:
372.97
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99%

form

solid

mp

140 °C (dec.) (lit.)

density

2.936 g/mL at 25 °C (lit.)

SMILES string

[H][N+]([H])([H])[H].[H][N+]([H])([H])[H].Cl[Pt--](Cl)(Cl)Cl

InChI

1S/4ClH.2H3N.Pt/h4*1H;2*1H3;/q;;;;;;+2/p-2

InChI key

QJIMNDWDOXTTBR-UHFFFAOYSA-L

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Application

  • Deactivation study of the hydrodeoxygenation of p-methylguaiacol: Studies catalysts prepared using ammonium tetrachloroplatinate(II), focusing on sustainable chemical processes relevant across academic research (Bouxin et al., 2017).

Features and Benefits

Reacts with creatinine (cat. no. 859702) to form various complexes such as [Pt4(creat)2Cl14]7- and [Pt4(creat)6]2- with applications in semiconductors, catalysis, mixed oxidation state studies, and electron conductivity.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Season S Chen et al.
Journal of hazardous materials, 397, 122431-122431 (2020-05-22)
The structural and chemical stability of UiO-66-NH2 and its simulated solar irradiation responsive characteristic make it a suitable metal-organic framework (MOF) candidate as photocatalytic material. Platinum nanoparticles (Pt NPs) are typically immobilized in MOF to enhance the photocatalytic efficiency. However
B C Chu et al.
Nucleic acids research, 20(10), 2497-2502 (1992-05-25)
We have prepared phosphorothioate-containing cyclic oligodeoxynucleotides that fold into 'dumbbells' containing CRE and TRE sequences, the binding sequences for the CREB and JUN proteins, respectively. Six phosphorothioate residues were introduced into each of the recognition sequences. K2PtCl4 crosslinks CRE to
Valentina Ljubomirova et al.
Analytica chimica acta, 614(2), 119-126 (2008-04-19)
A method for the separation of tetrachloroplatinate PtCl(4)(2-), and hexachloroplatinate PtCl(6)(2-), by solid-phase extraction, using a Dowex 1x10 anion exchange resin is proposed. The sequential elution and separation of PtCl(4)(2-), and PtCl(6)(2-) is achieved using selective complexing agents. The eluates
Z T Lalowicz et al.
Solid state nuclear magnetic resonance, 22(2-3), 373-393 (2002-12-10)
A detailed description of the diverse mobility of the ND4+ ions in the low-temperature ordered phase of (ND4)2PtCl4 is developed on the basis of single-crystal deuteron NMR spectra and site-selective T1 measurements. The ordered phase of (ND4)2PtCl4 consists of two
Francisco Tarazona-Vasquez et al.
The journal of physical chemistry. A, 111(5), 932-944 (2007-02-03)
Density functional theory is used to investigate the structure and energetics of the tetrachloroplatinate anion and its hydrolysis products at several degrees of hydration, as well as those of outer dendrimer pockets hosting such species. The number of water molecules

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