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156388

Sigma-Aldrich

Pentafluorophenylhydrazine

97%

Synonym(s):

(Perfluorophenyl)hydrazine, NSC 88334, PFPH

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About This Item

Linear Formula:
C6F5NHNH2
CAS Number:
Molecular Weight:
198.09
Beilstein:
747800
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

powder

mp

74-76 °C (lit.)

functional group

fluoro
hydrazine

SMILES string

NNc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C6H3F5N2/c7-1-2(8)4(10)6(13-12)5(11)3(1)9/h13H,12H2

InChI key

BYCUWCJUPSUFBX-UHFFFAOYSA-N

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Application

The product has been used to determine the purity of N-tert-butyl-N-[1-diethylphosphono-(2,2-dimethylpropyl)]nitroxide (DEPN) using 1H NMR spectroscopy.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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E E Stashenko et al.
Journal of chromatography. A, 779(1-2), 360-369 (1997-08-29)
High-resolution gas chromatography (HRGC) with electron-capture detection (ECD), nitrogen-phosphorus detection (NPD), flame ionization detection (FID) or with mass spectrometry-selected ion monitoring (MS-SIM) was used in the analysis of volatile carbonyl compounds. Eighteen carbonyl compounds that are typically produced during lipid
Rene Thomas Rivero et al.
Journal of cosmetic science, 55(4), 343-350 (2004-09-24)
The objective of this research was the application of headspace (HS)-solid-phase microextraction (SPME) for the quantitation of formaldehyde present in raw materials and cosmetic formulations. The formaldehyde was derivatized in situ first with pentafluorophenylhydrazine (PFPH), to form a derivative hydrazone.
Michael Otteneder et al.
Chemical research in toxicology, 15(3), 312-318 (2002-03-19)
Malondialdehyde is a ubiquitous product of lipid peroxidation that reacts with DNA to form premutagenic lesions. Principal among them is pyrimido-[1,2-alpha]purin-10(3H)-one (M(1)G). M(1)G has recently been found to be a reactive electrophile in DNA that couples with amines at basic
Elena E Stashenko et al.
Journal of chromatographic science, 44(6), 347-353 (2006-08-04)
Specific chromatographic methodologies are developed for the analysis of carboxylic acids (C(2)-C(6), benzoic) and aldehydes (C(2)-C(10)) of low molecular weight in diverse matrices, such as air, automotive exhaust gases, human breath, and aqueous matrices. For carboxylic acids, the method is
S Rochat et al.
Journal of chromatography. A, 1216(36), 6424-6432 (2009-08-05)
The GC-SNIF technique was used to obtain the olfactograms of shrimps, and their impact odorants were identified by MS hyphenated to the GC/olfactometric system and by comprehensive two-dimensional GC hyphenated to a time-of-flight MS. Confirming these identifications by their linear

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