148938
2-Iodopropane
contains copper as stabilizer, 99%
Synonym(s):
Isopropyl iodide
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About This Item
Linear Formula:
(CH3)2CHI
CAS Number:
Molecular Weight:
169.99
Beilstein:
1098244
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.498 (lit.)
bp
88-90 °C (lit.)
mp
−90 °C (lit.)
density
1.703 g/mL at 25 °C (lit.)
functional group
alkyl halide
SMILES string
CC(C)I
InChI
1S/C3H7I/c1-3(2)4/h3H,1-2H3
InChI key
FMKOJHQHASLBPH-UHFFFAOYSA-N
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General description
2-Iodopropane is an organ iodine compound. It is commonly used as a homolytic and heterolytic alkylating agent and in the preparation of the α-isopropoxymethylene blocking group. Additionally, it acts as an intermediator in the conversion of thiocarbonate to alkene.
Application
2-Iodopropane (Isopropyl iodide) was used to prepare butyric and isobutyric acid.
2-Iodopropane is used as an alkylating agent in the conversion of phenols, alcohols, oximes, carboxylic acids, and heteroatomic compounds (indoles, pyridines, purines, tetrazoles, pyrazoles, and amines) to give corresponding products.
2-Iodopropane is used as an alkylating agent in the conversion of phenols, alcohols, oximes, carboxylic acids, and heteroatomic compounds (indoles, pyridines, purines, tetrazoles, pyrazoles, and amines) to give corresponding products.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
107.6 °F - closed cup
Flash Point(C)
42 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Timur Coskun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
Joe Rashan et al.
Journal of AOAC International, 86(4), 694-702 (2003-09-26)
An alternative liquid chromatographic (LC) method was developed and validated for the simultaneous determination of methoxyl and 2-hydroxypropoxyl substituents in hypromellose and hypromellose acetate succinate. The method uses the hydriodic acid cleavage reaction, catalyzed by adipic acid, of the substituted
2-Iodopropane
Wilson PD and Hilmey DG
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
John J Orlando et al.
The journal of physical chemistry. A, 109(30), 6659-6675 (2006-07-13)
The reaction of Cl atoms with iodoethane has been studied via a combination of laser flash photolysis/resonance fluorescence (LFP-RF), environmental chamber/Fourier transform (FT)IR, and quantum chemical techniques. Above 330 K, the flash photolysis data indicate that the reaction proceeds predominantly
Development and validation of analytical procedure--control of residual 2-iodopropane in latanoprost.
Aleksandra Groman et al.
Acta poloniae pharmaceutica, 67(6), 673-676 (2011-01-15)
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