147532

1,3,5-Benzenetricarbonyl trichloride

98%

• Synonym(s): Benzene-1,3,5-tricarbonyl chloride, Trimesic acid trichloride, Trimesoyl chloride
• Linear Formula: C₆H₃(COCl)₃
• CAS Number: 4422-95-1
• Molecular Weight: 265.48
• Beilstein: 2940936
• EC Number: 224-594-8
• MDL number: MFCD00000679
• UNSPSC Code: 12352100
• PubChem Substance ID: 24848560
• NACRES: NA.23

Properties

• Quality Level: 200
• Assay: 98%
• form: solid
• bp: 180 °C/16 mmHg (lit.)
• mp: 32-38 °C (lit.)
• solubility: chloroform: soluble 10%, clear to very slightly hazy, colorless to faintly yellow
• density: 1.487 g/mL at 25 °C (lit.)
• SMILES string: ClC(=O)c1cc(cc(c1)C(Cl)=O)C(Cl)=O
• InChI: 1S/C9H3Cl3O3/c10-7(13)4-1-5(8(11)14)3-6(2-4)9(12)15/h1-3H
• InChI key: UWCPYKQBIPYOLX-UHFFFAOYSA-N

Description

General description

1,3,5-Benzenetricarbonyl trichloride reacts with propargyl alcohol to yield triprop-2-ynyl benzene-1,3,5-tricarboxylate.

Application

1,3,5-Benzenetricarbonyl trichloride was used in the synthesis of chiral azoaromatic dendrimeric systems. It was used to study the structure of activated composite membranes containing organophosphorus extractants as carriers. It was the starting material for two tritopic amides derived from 3- and 4-methylaminopyridine which self-assembled into nanoballs on treatment with palladium(II) nitrate in DMSO.

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H314,H317
• Precautionary Statements: P260 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): 230.0 °F - closed cup
• Flash Point(C): 110 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves