140392
4-Hydroxy-3,5-dimethylbenzaldehyde
95%
Synonym(s):
3,5-Dimethyl-4-hydroxybenzaldehyde
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About This Item
Linear Formula:
HOC6H2(CH3)2CHO
CAS Number:
Molecular Weight:
150.17
Beilstein:
1908717
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
95%
mp
112-114 °C (lit.)
functional group
aldehyde
SMILES string
[H]C(=O)c1cc(C)c(O)c(C)c1
InChI
1S/C9H10O2/c1-6-3-8(5-10)4-7(2)9(6)11/h3-5,11H,1-2H3
InChI key
UYGBSRJODQHNLQ-UHFFFAOYSA-N
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Application
4-Hydroxy-3,5-dimethylbenzaldehydewas used as reagent during the phase transfer catalyzed polymerization of 4-hydroxy-3,5-dimethylbenzyl alcohol. It was used as starting reagent during the synthesis of 2,4,6-trimethylphenol.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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P R Ortiz de Montellano et al.
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Chloroperoxidase and H2O2 oxidize styrene to styrene oxide and phenylacetaldehyde but not benzaldehyde. The epoxide oxygen is shown by studies with H2(18)O2 to derive quantitatively from the peroxide. The epoxidation of trans-[1-2H]styrene by chloroperoxidase proceeds without detectable loss of stereochemistry
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Shimizu M, et al.
Tetrahedron Letters, 32(18), 2053-2056 (1991)
Phase transfer catalyzed polymerization of 4-hydroxy-3, 5-dimethylbenzyl alcohol and copolymerization of 4-bromo-2, 6-dimethylphenol with 4-hydroxy-3, 5-dimethylbenzyl alcohol.
Wang JH and Percec V.
Polym. Bull., 25(1), 25-32 (1991)
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