131377
1,10-Phenanthroline
≥99%
Synonym(s):
o-phenanthroline
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All Photos(2)
About This Item
Empirical Formula (Hill Notation):
C12H8N2
CAS Number:
Molecular Weight:
180.21
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
39210124
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥99%
form
powder
mp
114-117 °C (lit.)
SMILES string
c1cnc2c(c1)ccc3cccnc23
InChI
1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H
InChI key
DGEZNRSVGBDHLK-UHFFFAOYSA-N
Gene Information
human ... FNTA(2339)
Application
1,10-Phenanthroline can be used as:
- A cathode buffer layer to improve the efficiency of organic solar cells.
- A conventional chelator to study its efficacy in Fenton′s reaction-luminol chemiluminescence system.
- A ligand in mild, copper (II)-catalyzed cross-coupling of organoboronic acids and sulfinate salts, leading to aryl- and alkenylsulfones.
- A versatile ligand employed in the spectrophotometric determination of metals and photocatalytic reduction of carbon dioxide.
- A building block for metallomacrocycles.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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In vitro screening of Fe2+-chelating effect by a Fenton's reaction-luminol chemiluminescence system.
Mitsuhiro Wada et al.
Luminescence : the journal of biological and chemical luminescence, 29(7), 955-958 (2014-01-10)
In vitro screening of a Fe(2+) -chelating effect using a Fenton's reaction-luminol chemiluminescence (CL) system is described. The luminescence between the reactive oxygen species generated by the Fenton's reaction and luminol was decreased on capturing Fe(2+) using a chelator. The
Neville S Ng et al.
Dalton transactions (Cambridge, England : 2003), 42(9), 3196-3209 (2012-12-13)
Copper(II) (1(Cu)-21(Cu)) and previously established experimental anticancer platinum(II) metallointercalator complexes (1(Pt)-16(Pt)) have been prepared and investigated for their antimicrobial properties. These complexes are of the general structure [M(I(L))(A(L))](2+) where I(L) represents functionalised 1,10-phenanthrolines (1(IL)-10(IL)), and A(L) represents 1,2-diaminoethane, 1S,2S- or
Catalysis by Metal Complexes, 14, 217-217 (1993)
Luiza Notini et al.
Environmental science & technology, 53(15), 8883-8891 (2019-07-10)
Surface defects have been shown to facilitate electron transfer between Fe(II) and goethite (α-FeOOH) in abiotic systems. It is unclear, however, whether defects also facilitate microbial goethite reduction in anoxic environments where electron transfer between cells and Fe(III) minerals is
Chunming Sun et al.
ACS applied materials & interfaces, 6(2), 739-744 (2014-01-07)
We reported a significant improvement in the efficiency of organic solar cells by introducing hybrid TiO2:1,10-phenanthroline as a cathode buffer layer. The devices based on polymer thieno[3,4-b]thiophene/benzodithiophene:[6,6]-phenyl C71-butyric acid methyl ester (PTB7:PC71BM) with hybrid buffer layer exhibited an average power
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