122459
Ferrocenecarboxaldehyde
98%
Synonym(s):
Cyclopentadienyl(formylcyclopentadienyl)iron
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About This Item
Empirical Formula (Hill Notation):
C11H10FeO
CAS Number:
Molecular Weight:
214.04
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
solid
reaction suitability
core: iron
reagent type: catalyst
mp
118-120 °C (lit.)
functional group
aldehyde
storage temp.
2-8°C
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.[H]C(=O)[C]2[CH][CH][CH][CH]2
InChI
1S/C6H5O.C5H5.Fe/c7-5-6-3-1-2-4-6;1-2-4-5-3-1;/h1-5H;1-5H;
InChI key
UQTCQJVPLIVCAX-UHFFFAOYSA-N
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Application
Used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Cesar Mendoza-Martínez et al.
European journal of medicinal chemistry, 92, 314-331 (2015-01-13)
A series of quinazoline-2,4,6-triamine were synthesized and evaluated in vitro against Leishmania mexicana. Among them, N(6)-(ferrocenmethyl)quinazolin-2,4,6-triamine (H2) showed activity on promastigotes and intracellular amastigotes, as well as low cytotoxicity in mammalian cells. Docking and electrochemical studies showed the importance of both
Zhipeng Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 27(4), 1286-1291 (2010-11-04)
Single-component microcapsules were fabricated by the in situ reaction of ferrocenecarboxaldehyde (Fc-CHO) with poly(allylamine hydrochloride) (PAH) doped inside CaCO(3) microparticles, followed by core removal. The PAH-Fc microcapsules had very thick shells with remnant PAH-Fc inside, leading to a robust capsule
Mina Okochi et al.
Biotechnology and bioengineering, 90(1), 14-19 (2005-03-01)
Labeling of ferrocenecarboaldehyde (Fc-CHO) to immunoglobulin G (IgG) via formation of Schiff-base and its reduction was investigated for construction of an electrochemical probe for miniaturized amperometric flow immunoassay. Approximately eight molecules of Fc-CHO were labeled to IgG and the reversible
C Xu et al.
Fresenius' journal of analytical chemistry, 367(6), 593-595 (2001-02-28)
A ferrocenecarboxaldehyde (FCA) labeled DNA probe is used for the first time in the study of DNA damage and protection. The electrochemically active reagent FCA was labeled successfully on to a denatured calf-thymus DNA by 1-ethyl-3- (3-dimethyl-aminopropyl) carbodiimide (EDC). The
John Spencer et al.
Dalton transactions (Cambridge, England : 2003), (6)(6), 918-921 (2009-01-29)
The Knoevenagel condensation of 1,3-dihydro-2H-indol-2-one with ferrocene carboxaldehyde afforded an approximate 2:1 mixture of the geometrical isomers (E)- and (Z)-3-ferrocenylmethylidene-1,3-dihydro-2H-indol-2-one respectively in an overall 67% yield; the air and solution-stable isomers were readily separated by preparative thin layer chromatography and
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