117277
Bis(4-bromophenyl) ether
99%
Synonym(s):
4-Bromophenyl ether
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About This Item
Linear Formula:
(BrC6H4)2O
CAS Number:
Molecular Weight:
328.00
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
form
solid
bp
338-340 °C (lit.)
mp
61-63 °C (lit.)
functional group
bromo
SMILES string
Brc1ccc(Oc2ccc(Br)cc2)cc1
InChI
1S/C12H8Br2O/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H
InChI key
YAWIAFUBXXPJMQ-UHFFFAOYSA-N
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Application
Bis-(4-bromophenyl)-ether has been used in the preparation of 4-[4′-(diethoxyphosphoryl)phenoxy]phenyl-phosphonic acid diethyl ester.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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M Mar Gómez-Alcántara et al.
Inorganic chemistry, 43(17), 5283-5293 (2004-08-18)
Commercial bis-(4-bromophenyl)-ether, [BrC(6)H(4)](2)-O, has been used to prepare 4-[4'-(diethoxyphosphoryl)phenoxy]phenyl-phosphonic acid diethyl ester, [(CH(3)CH(2))(2)O(3)P-C(6)H(4)](2)-O, (I) following a slight modification of the Michaelis-Arbuzov reaction. The acid hydrolysis of I gave 4-(4'-phosphonophenoxy)phenyl phosphonic acid, [H(2)O(3)P-C(6)H(4)](2)-O (II), and both compounds have been characterized by
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