Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Molecules (Basel, Switzerland) (2013-05-28)

Jana Doháňošová, Tibor Gracza

ABSTRACT

The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.

MATERIALS

Product Number

Brand

Product Description

287474

Sigma-Aldrich

Palladium, foil, thickness 0.5 mm, 99.9% trace metals basis

348643

Sigma-Aldrich

Palladium, foil, thickness 0.25 mm, 99.98% trace metals basis

348678

Sigma-Aldrich

Palladium, foil, thickness 1.0 mm, 99.9% trace metals basis

203998

Sigma-Aldrich

Palladium, powder or granules, 99.99% trace metals basis

326666

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Palladium, powder, <1 μm, ≥99.9% trace metals basis

267112

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Palladium, wire, diam. 1.0 mm, 99.9% trace metals basis

267120

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267082

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373206

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348694

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464651

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686468

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Palladium, nanopowder, <25 nm particle size (TEM), ≥99.5%

203939

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Palladium, powder, 99.995% trace metals basis

GF69074916

Palladium, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.75%

GF55245821

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

GF60234533

Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.99+%

GF23374661

Palladium, foil, 8mm disks, thickness 0.50mm, as rolled, 99.95%

GF60084424

Palladium, foil, light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

GF44874995

Palladium, foil, light tested, 100x100mm, thickness 0.047mm, as rolled, 99.95%

GF94632576

Palladium, foil, light tested, 100x100mm, thickness 0.075mm, as rolled, 99.95%

GF74894136

Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.95%

GF06323295

Palladium, wire reel, 0.5m, diameter 0.02mm, as drawn, 99.95%

GF25956917

Palladium, wire reel, 2m, diameter 0.25mm, as drawn, 99.99+%

GF36099311

Palladium, wire reel, 10m, diameter 0.25mm, hard, 99.95%

GF81435146

Palladium, rod, 100mm, diameter 2.0mm, 99.95%

GF73152648

Palladium, rod, 10mm, diameter 6.0mm, 99.95%

GF99483351

Palladium, foil, not light tested, 50x50mm, thickness 0.008mm, 99.95%

GF40398352

Palladium, wire reel, 1m, diameter 0.25mm, hard, 99.95%

GF11001564

Palladium, microfoil, disks, 25mm, thinness 0.05μm, specific density 63.6μg/cm², permanent mylar 3.5μm support, 99.99%

GF39094904

Palladium, tube, 50mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, as drawn, 99.95%