Chemical & pharmaceutical bulletin, 60(3), 285-299 (2012-03-03)
It is known that propargylic compounds having an ester and a halide at the propargylic positions react with palladium complexes leading to π-propargylpalladium and allenylpalladium complexes, which cause various transformations in the presence of the reactants. The aim of the
Synthesis of heterocycles via palladium-catalyzed carbonylations.
Copper and palladium catalysts are critically important in numerous commercial chemical processes. Improvements in the activity, selectivity and scope of these catalysts could drastically reduce the environmental impact, and increase the sustainability, of chemical reactions. One rapidly developing strategy for
Update 1 of: Synthesis and functionalization of indoles through palladium-catalyzed reactions.
Sandro Cacchi et al.
Chemical reviews, 111(5), PR215-PR283 (2011-05-12)
A novel palladium-catalyzed intramolecular oxidative alkylation of unactivated olefins is described. This protocol was devised to solve one of the drawbacks of the original palladium-catalyzed cycloalkenylation that we developed. We call this new procedure the 'second generation palladium-catalyzed cycloalkenylation'. This
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