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Trifloxystrobin

PESTANAL®, analytical standard

Synonym(s):

Methyl (E)-α-methoxyimino-2-[(E)-1-(3-trifluoromethylphenyl)ethylidenaminooxymethyl]phenylacetate

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About This Item

Empirical Formula (Hill Notation):
C20H19F3N2O4
CAS Number:
141517-21-7
Molecular Weight:
408.37
MDL number:
MFCD09953763
UNSPSC Code:
41116107
PubChem Substance ID:
329757189
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CO\N=C(\C(=O)OC)c1ccccc1CO\N=C(/C)c2cccc(c2)C(F)(F)F

InChI

1S/C20H19F3N2O4/c1-13(14-8-6-9-16(11-14)20(21,22)23)24-29-12-15-7-4-5-10-17(15)18(25-28-3)19(26)27-2/h4-11H,12H2,1-3H3/b24-13+,25-18+

InChI key

ONCZDRURRATYFI-TVJDWZFNSA-N

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General description

Trifloxystrobin is classified under the group of new strobilurin fungicides applied in viticulture for the control of downy (Plasmopara viticola) and powdery (Uncinula necator) mildews. Its mode of action involves the inhibition of the mitochondrial respiration by means of its binding at the Qo site of cytochrome b, present in the inner mitochondrial membrane of the fungi.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Trifloxystrobin may be used as an analytical reference standard for the determination of the analyte in wine, fruits and vegetables, and rice and soil samples by various chromatographic techniques.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H317,H362,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Lact. - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH8239
BCCF1586
BCBW5458
BCBS0306V
SZBE022XV

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Validation and global uncertainty of a liquid chromatographic with diode array detection method for the screening of azoxystrobin, kresoxim-methyl, trifloxystrobin, famoxadone, pyraclostrobin and fenamidone in grapes and wine.
de Melo Abreu S, et al.
Analytica Chimica Acta, 573, 291-297 (2006)
William H Mimbs et al.
Chemosphere, 159, 275-281 (2016-06-15)
Wetlands in the Rainwater Basin (RWB) of Nebraska are commonly in close proximity to or embedded within row-crop agriculture. Several fungicides and bifenthrin are applied aerially to corn throughout the RWB during tassel stage. Thus, aerial spray drift and runoff
Simultaneous determination of trifloxystrobin and trifloxystrobin acid residue in rice and soil by a modified quick, easy, cheap, effective, rugged, and safe method using ultra high performance liquid chromatography with tandem mass spectrometry.
Chen X, et al.
Journal of Separation Science, 37(13), 1640-1647 (2014)
Determination of tebuconazole, trifloxystrobin and its metabolite in fruit and vegetables by a Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method using gas chromatography with a nitrogen-phosphorus detector and ion trap mass spectrometry.
Liu X, et al.
Biomedical Chromatography, 25(10), 1081-1090 (2011)
H R Kutcher et al.
Plant disease, 102(9), 1828-1833 (2018-08-21)
A complex of leaf-spotting diseases-tan spot, the Septoria complex, spot blotch, and powdery mildew-are frequently observed on winter wheat in western Canada; however, there are few studies indicating varietal differences in reaction to these diseases or the benefit of fungicide
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