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805459

Sigma-Aldrich

DPEPO

Synonym(s):

Bis[2-(diphenylphosphino)phenyl] ether oxide

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About This Item

Empirical Formula (Hill Notation):
C36H28O3P2
CAS Number:
808142-23-6
Molecular Weight:
570.55
UNSPSC Code:
12352103
PubChem Substance ID:
329768938
NACRES:
NA.23

Assay

98%

Quality Level

100

form

powder

mp

276-281 °C

Orbital energy

HOMO 6.1 eV 
LUMO 2.0 eV 

OLED Device Performance

ITO/a-NPD/mCP/ bis-PXZ-OXD (6 wt%):DPEPO/DPEPO/TPBi/LiF/Al

  • Max. EQE: 14.9 %

ITO/a-NPD/mCP/ bis-PXZ-TDZ (6 wt%):DPEPO/DPEPO/TPBi/LiF/Al
  • Max. EQE: 10.0 %

SMILES string

O=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=C(OC4=CC=CC=C4P(C5=CC=CC=C5)(C6=CC=CC=C6)=O)C=CC=C3

InChI

1S/C36H28O3P2/c37-40(29-17-5-1-6-18-29,30-19-7-2-8-20-30)35-27-15-13-25-33(35)39-34-26-14-16-28-36(34)41(38,31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H

InChI key

ATTVYRDSOVWELU-UHFFFAOYSA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Kuan-Yu Liao et al.
Inorganic chemistry, 54(8), 4029-4038 (2015-04-08)
Tetradentate bis(pyridyl azolate) chelates are assembled by connecting two bidentate 3-trifluoromethyl-5-(2-pyridyl)azoles at the six position of pyridyl fragment with the tailored spiro-arranged fluorene and/or acridine functionalities. These new chelates were then utilized in synthesizing a series of Pt(II) metal complexes
Effect of Atom Substitution in Chalcogenodiazole-Containing Thermally Activated Delayed Fluorescence Emitters on Radiationless Transition
Tanaka et al.
The Journal of Physical Chemistry C, 119(6), 2948-2955 (2015)
Efficient blue organic light-emitting diodes employing thermally activated delayed fluorescence
Zhang et al.
Nature Photonics, 8(4), 326-332 (2014)
Qisheng Zhang et al.
Journal of the American Chemical Society, 134(36), 14706-14709 (2012-08-31)
Efficient thermally activated delayed fluorescence (TADF) has been characterized for a carbazole/sulfone derivative in both solutions and doped films. A pure blue organic light emitting diode (OLED) based on this compound demonstrates a very high external quantum efficiency (EQE) of
Mounggon Kim et al.
Advanced materials (Deerfield Beach, Fla.), 27(15), 2515-2520 (2015-03-11)
High quantum efficiency above 18% and extended lifetime three times longer than that of phosphorescent organic light-emitting diodes (OLEDs) are demonstrated in blue thermally activated delayed fluorescent OLEDs.

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