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92877

Sigma-Aldrich

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

≥95.0%

Synonym(s):

Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II), Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex, PdCl2(dppb)

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About This Item

Empirical Formula (Hill Notation):
C28H28Cl2P2Pd
CAS Number:
Molecular Weight:
603.80
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

Assay

≥95.0%

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

SMILES string

Cl[Pd]Cl.C(CCP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI

1S/C28H28P2.2ClH.Pd/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;;;/h1-12,15-22H,13-14,23-24H2;2*1H;/q;;;+2/p-2

InChI key

JQXJBXVWVPVTOO-UHFFFAOYSA-L

Application

catalyst for coupling reactions

Other Notes

Palladium-catalyzed cross-coupling and coupling reactions

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Bjork, P.; Hornfeldt, A.-B. et al.
Journal of Heterocyclic Chemistry, 31, 1161-1161 (1994)
MethCohn, O.; Jiang, H.
Journal of the Chemical Society. Perkin Transactions 1, 3737-3737 (1998)
M. Kranenburg et al.
European Journal of Inorganic Chemistry, 155-155 (1998)
Minato, K.; Suzuki, K et al.
Journal of the Chemical Society. Chemical Communications, 511-511 (1984)
B.L. Shaw
Chemical Communications (Cambridge, England), 1863-1863 (1998)

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