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911607

Sigma-Aldrich

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6

≥95%

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About This Item

Empirical Formula (Hill Notation):
C36H22F16IrN4O2P
CAS Number:
Molecular Weight:
1069.75
UNSPSC Code:
12161600
NACRES:
NA.22

Assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

photocatalyst activation

465 nm

Application

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the trifluoromethylation of alkyl bromides.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

related product

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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David J P Kornfilt et al.
Journal of the American Chemical Society, 141(17), 6853-6858 (2019-04-16)
Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to Csp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has

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