69227
2-(Methylsulfonyl)ethyl 4-nitrophenyl carbonate
≥99.0% (C)
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About This Item
Empirical Formula (Hill Notation):
C10H11NO7S
CAS Number:
Molecular Weight:
289.26
Beilstein:
1890569
EC Number:
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
Recommended Products
Assay
≥99.0% (C)
mp
100-103 °C
storage temp.
2-8°C
SMILES string
CS(=O)(=O)CCOC(=O)Oc1ccc(cc1)[N+]([O-])=O
Other Notes
Reagent to introduce the MSOC-group, a versatile amino protective function with: extreme acid stability, high base lability and high polarity which enhances solubility in polar solvents.; MSOC resists hydrogenation but does not poison the catalyst
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[Hormone-receptor interactions. Syntheses of alpha-melanotropin and of informational sequences thereof with the aid of alcali-labile protecting groups (author's transl)].
A Eberle et al.
Helvetica chimica acta, 58(7), 2106-2129 (1975-11-05)
Helvetica Chimica Acta, 60, 2895-2895 (1977)
G I Tesser et al.
International journal of peptide and protein research, 7(4), 295-305 (1975-01-01)
A new amino protecting group, the methylsulfonylethyloxycarbonyl (Msc) group, is described which combines well with other familiar groups (benzyloxycarbonyl, t-butyloxycarbonyl) in peptide syntheses. Its main characteristics are an extreme acid stability, a high base lability and a high polarity which
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