594458
4-Methoxyphenyl isocyanide
97%
Synonym(s):
1-Isocyano-4-methoxybenzene, 4-Isocyanoanisole, 4-Methoxy-1-isocyanobenzene, 4-Methoxyphenyl isonitrile, Anisyl isonitrile, p-Anisyl isocyanide, p-Anisyl isonitrile, p-Methoxyphenyl isocyanide, p-Methoxyphenyl isonitrile
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About This Item
Linear Formula:
H3COC6H4NC
CAS Number:
Molecular Weight:
133.15
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
mp
29-33 °C (lit.)
storage temp.
−20°C
SMILES string
COc1ccc(cc1)[N+]#[C-]
InChI
1S/C8H7NO/c1-9-7-3-5-8(10-2)6-4-7/h3-6H,2H3
InChI key
MIEQKTRWKZYUPY-UHFFFAOYSA-N
Application
4-Methoxyphenyl isocyanide can be used to synthesize N-(isoquinolin-1-yl)-formamides via reaction with 2-alkynylbenzaldoximes in the presence of silver trifluoromethanesulfonate and bismuth triflate.[1]
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
224.6 °F - closed cup
Flash Point(C)
107 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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"Multicatalytic Tandem Reactions of 2-Alkynylbenzaldoximes with Isocyanides"
Chen Z, et al.
AZo Journal of Materials Online, 351(16), 2702- 2708 (2009)
Hideaki Komiyama et al.
Nanotechnology, 26(39), 395302-395302 (2015-09-12)
We present an alternative approach to fabricating hexagonally arranged nanodot arrays of various metals by seed-mediated electroless plating with a cylinder-forming block copolymer thin film, PEO-b-PMA(Az), as a scaffold. Metal ions were selectively incorporated into PEO cylinders, followed by their
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