339636
exo-N-Hydroxy-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide
98%
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About This Item
Empirical Formula (Hill Notation):
C8H7NO4
CAS Number:
Molecular Weight:
181.15
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Assay
98%
mp
194 °C (dec.) (lit.)
solubility
THF: soluble 10 mg/mL, clear, colorless
SMILES string
ON1C(=O)[C@H]2C3OC(C=C3)[C@H]2C1=O
InChI
1S/C8H7NO4/c10-7-5-3-1-2-4(13-3)6(5)8(11)9(7)12/h1-6,12H/t3-,4+,5?,6?
InChI key
PPVGNPSAUJFBJY-LAXKNYFCSA-N
General description
exo-N-Hydroxy-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide undergoes cross-coupling with aryl boronic acid for ROMP-based O-alkylhydroxylamine parallel synthesis.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Jamerson Carneiro de Oliveira et al.
Carbohydrate polymers, 250, 116966-116966 (2020-10-15)
The Diels-Alder reaction is a promising click chemistry for the design of advanced materials from cellulose nanocrystals (CNCs). Transferring such chemistry to cellulose nanocrystals requires the precise grafting of reactive Diels-Alder moeities under heterogeneous conditions without compromising the nanocrystals morphology.
Florence S Gaucher-Wieczorek et al.
Journal of combinatorial chemistry, 12(5), 655-658 (2010-09-14)
The parallel synthesis of O-aryloxyamines remains an unfulfilled need in the field of medicinal chemistry and fragment-based approaches. To fill this gap a solution-phase two-step process based on (1) a copper-catalyzed cross-coupling of aryl boronic acids with a fluorous tagged
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