T6601
3,4,5,6-Tetrachloro-1,2-benzoquinone
97%
Synonym(s):
o-Chloranil
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About This Item
Linear Formula:
C6Cl4(=O)2
CAS Number:
Molecular Weight:
245.88
Beilstein:
1309782
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
mp
126-129 °C (lit.)
storage temp.
2-8°C
SMILES string
ClC1=C(Cl)C(=O)C(=O)C(Cl)=C1Cl
InChI
1S/C6Cl4O2/c7-1-2(8)4(10)6(12)5(11)3(1)9
InChI key
VRGCYEIGVVTZCC-UHFFFAOYSA-N
Gene Information
human ... ACHE(43) , BCHE(590) , CES1(1066)
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Frank Wurche et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 10(11), 2707-2721 (2004-06-15)
The effect of pressure on the oxidation of hydroarenes 3-9 with 2,3-dichloro-5,6-dicyano-1,4-quinone (DDQ; 1 a) or o-chloranil (10), leading to the corresponding arenes, has been investigated. The activation volumes were determined from the pressure dependence of the rate constants of
Asim Kumar Ray et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(7), 1375-1378 (2002-06-27)
o-Chloranil has been shown to form 1:1 molecular complexes with pyridine and 2-, 3- and 4-picolines in CCl4 medium. Isosbestic points have been found but charge-transfer bands could not be detected. The formation constants of the complexes exhibit a very
Mirosława Kot et al.
Journal of enzyme inhibition and medicinal chemistry, 21(5), 537-542 (2006-12-30)
Tetrachloro-o-benzoquinone (TCoBQ) and tetrachloro-p-benzoquinone (TCpBQ) were studied as inhibitors of jack bean urease in 20 mM phosphate buffer, pH 7.0, 1 mM EDTA, 25 degrees C. The mechanisms of inhibition were evaluated by analysis of the progress curves obtained with
F Kader et al.
Journal of agricultural and food chemistry, 47(11), 4625-4630 (1999-12-20)
Caffeic acid o-quinone (CQ) was prepared by oxidation of caffeic acid with o-chloranil in organic media. The reaction between the purified CQ and cyanidin 3-glucoside (Cy 3-glc, o-diphenolic anthocyanin) was monitored by HPLC, and quantitative analyses were performed to establish
B E Bengtsson et al.
Ecotoxicology and environmental safety, 15(1), 62-71 (1988-02-01)
The effects of tetrachloro-1,2-benzoquinone (TCQ), a component in bleached kraft mill effluents (BKME), on vertebral and physiological parameters were investigated in juvenile fourhorn sculpin, Myoxocephalus quadricornis L. After about 4.5 months of exposure to 0.1 and 0.5 mg TCQ/liter in
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