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Sigma-Aldrich

AlPhos Pd G6 OTf

Synonym(s):

AlPhos OAC precatalyst OTf

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About This Item

Empirical Formula (Hill Notation):
C60H71F10O4PPdS
CAS Number:
Molecular Weight:
1215.65
UNSPSC Code:
12352100
NACRES:
NA.22

form

powder

Quality Level

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

AlPhos Pd G6 OTf is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Bryan T Ingoglia et al.
Organic letters, 19(11), 2853-2856 (2017-05-13)
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts

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