710857
Iron(III) chloride solution
0.2 M in 2-methyltetrahydrofuran
Synonym(s):
Ferric chloride solution
About This Item
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form
solution
Quality Level
reaction suitability
core: iron
reagent type: catalyst
greener alternative product characteristics
Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
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concentration
0.2 M in 2-methyltetrahydrofuran
refractive index
n20/D 1.414
density
0.868 g/mL at 25 °C
greener alternative category
, Aligned
SMILES string
Cl[Fe](Cl)Cl
InChI
1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChI key
RBTARNINKXHZNM-UHFFFAOYSA-K
General description
Application
- As a mild oxidant for phenolic coupling reaction.
- In dimerizing aryllithiumsand ketone enolates.
- As a mild Lewis acid catalyst to catalyzes ene reactions.
- In Nazarov cyclizations, Michael additions, and acetonation reactions.
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
14.0 °F - closed cup
Flash Point(C)
-10.0 °C - closed cup
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