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Sigma-Aldrich

Basolite® A100

greener alternative

produced by BASF

Synonym(s):

Aluminum terephthalate, MIL-53(Al)

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About This Item

Empirical Formula (Hill Notation):
C8H5AlO5
Molecular Weight:
208.10
UNSPSC Code:
26111700
NACRES:
NA.23

grade

produced by BASF

form

tablet

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

1100-1500 m2/g

particle size distribution

31.55 μm (D50)

bulk density

0.4 g/cm3

greener alternative category

, Enabling

General description

Basolite (TM) A100 is also known as MIL-53(Al). It is an ultramicroporous metal framework (MOF).
Basolite®A100 is a microporous metal-organic framework (MOF), which consists of three-dimensional networks with micropores up to 900 pm in diameter. It has characteristics that are identical to MIL-53(Al) as it contains octahedral AlO4(OH)2 units connected through 1,4-benzenedicarboxylate ligands. It allows the formation of a framework with a high specific surface of 1084 m2g-1 area and a pore volume of about 0.51 cm2g-1.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Basolite (TM) A100 was used in the separation of C8-alkylaromatic compounds.
Basolite®A100 is majorly used in the binary gas separation of CO2/CH4 and CO2/N2. It can also be used for gas adsorption (hydrogen gas) and for the supercritical adsorption of CO2.

Other Notes

can be reactivated at 200°C (vacuum)

Legal Information

Basolite is a registered trademark of BASF SE

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Statements

H319,H360D

Hazard Classifications

Eye Irrit. 2 - Repr. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A complete procedure for acidic gas separation by adsorption on MIL-53 (Al)
Heymans N, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 154(1), 93-99 (2012)
MOF-containing mixed-matrix membranes for CO2/CH4 and CO2/N2 binary gas mixture separations
Basu S, et al.
Separation and Purification Technology, 81(1), 31-40 (2011)
A combined computational and experimental study of high pressure and supercritical CO2 adsorption on Basolite MOFs
Deniz E, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 175(1), 34-42 (2013)
Christian Serre et al.
Journal of the American Chemical Society, 124(45), 13519-13526 (2002-11-07)
The first three-dimensional chromium(III) dicarboxylate, MIL-53as or Cr(III)(OH) x [O(2)C-C(6)H(4)-CO(2)].[HO(2)C-C(6)H(4)-CO(2)H](0.75), has been obtained under hydrothermal conditions (as: as-synthesized). The free acid can be removed by calcination giving the resulting solid, MIL-53ht or Cr(III)(OH) x [O(2)C-C(6)H(4)-CO(2)]. At room temperature, MIL-53ht adsorbs
Gérard Férey et al.
Chemical communications (Cambridge, England), (24), 2976-2977 (2004-01-06)
Hydrogen adsorption has been studied in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+); these solids show a hydrogen storage capacity of 3.8 and 3.1 wt.% respectively when loaded at 77 K under 1.6 MPa.
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