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650412

Sigma-Aldrich

Borane tetrahydrofuran complex solution

1.0 M in THF, contains 0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer

Synonym(s):

Borane-THF (1:1), Borane-THF complex (1:1)

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About This Item

Linear Formula:
BH3OC4H8
CAS Number:
Molecular Weight:
85.94
Beilstein:
3668402
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:

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contains

0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer

Quality Level

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

density

0.880 g/mL at 25 °C

functional group

ether

storage temp.

2-8°C

SMILES string

B.C1CCOC1

InChI

1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3

InChI key

RMCYTHFAWCWRFA-UHFFFAOYSA-N

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Application

This useful reagent for reductions[1] and other transformations is now safer in transport utilizing this new stabilizer
Used to reduce nylon surface amide groups to secondary amines.[2]

Packaging

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3 - Water-react 1

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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    This paper presents a highly stereoselective synthesis of trifluoro- or difluoromethylated olefins via an S(N)2' type fluorination or reductions of gem-difluorinated vinyloxiranes. Their fluorination with HF-Py furnished trifluoromethylated allylic alcohols with exclusive E selectivity. On the other hand, their reduction
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