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GC Stationary Phase

phase 1,2,3-tris(2-Cyanoethoxy)propane (TCEP), bottle of 50 g

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About This Item

EC Number:
UNSPSC Code:
23151817

packaging

bottle of 50 g

parameter

0-175 °C temp. range

technique(s)

gas chromatography (GC): suitable

matrix active group

1,2,3-tris(2-Cyanoethoxy)propane (TCEP) phase

solubility

chloroform/methanol (2:1): soluble

column type

packed GC

General description

GC methods are divided into two classes depending on the nature of stationary phases; gas-solid chromatography (GSC) and gas-liquid chromatography (GLC). GSC has solid adsorptive material and solute particles are removed from mobile phase by electrostatic forces. GLC has a thin layer of liquid coated or bonded on the surface of an inert particle or on the walls of the column where solute particles are retained in the liquid phase based on their partition coefficients. The primary necessity of a stationary phase is to provide sample separation sustaining phase integrity over a reasonable period of time. It should be stable for the chemical and thermal changes. Selectivity, peak symmetry, analysis time, degree of separation, peak tailing are few parameters to consider for choosing a stationary phase. 1,2,3-tris(2-Cyanoethoxy)propane (TCEP) is diviylimidazolium bistriflamide ionic liquid which improves oxygen and moisture stability.
Synthesized specifically to be purer, of narrow molecular weight range, and without trace catalysts or impurities for use as a GC stationary phase.

Application

TCEP may be used as stationary phase, to study the adsorption effects on the surface of the support/or stationary phase in gas-liquid partition chromatography.

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Adsorption effects in gas-liquid partition chromatography.
Komaita, Toshiki
Journal of Chromatography A, 114, 1-14 (1975)
Kenneth R. Seddon, Natalia V. Plechkova
Ionic Liquids Uncoiled: Critical Expert Overviews (2012)
Dominic Kamps et al.
Cell reports, 33(9), 108467-108467 (2020-12-03)
Local cell contraction pulses play important roles in tissue and cell morphogenesis. Here, we improve a chemo-optogenetic approach and apply it to investigate the signal network that generates these pulses. We use these measurements to derive and parameterize a system
Joost Snijder et al.
Immunity, 48(4), 799-811 (2018-04-19)
Epstein-Barr virus (EBV) is a causative agent of infectious mononucleosis and is associated with 200,000 new cases of cancer and 140,000 deaths annually. Subunit vaccines against this pathogen have focused on the gp350 glycoprotein and remain unsuccessful. We isolated human
Darin L Wiesner et al.
Cell host & microbe, 27(4), 614-628 (2020-03-05)
Airway epithelium is the first body surface to contact inhaled irritants and report danger. Here, we report how epithelial cells recognize and respond to aeroallergen alkaline protease 1 (Alp1) of Aspergillus sp., because proteases are critical components of many allergens

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