40241

(S)-(−)-N,N-Dimethyl-1-ferrocenylethylamine

≥98.0% (T)

• Synonym(s): (S)-(−)-[1-(Dimethylamino)ethyl]ferrocene
• Empirical Formula (Hill Notation): C₁₄H₁₉FeN
• CAS Number: 31886-57-4
• Molecular Weight: 257.15
• MDL number: MFCD00066272
• UNSPSC Code: 12352116
• PubChem Substance ID: 57649950
• NACRES: NA.22

Properties

• Assay: ≥98.0% (T)
• optical activity: [α]20/D −14±1°, c = 1.5% in ethanol
• color: dark brown
• bp: 120-121 °C/0.7 mmHg (lit.)
• density: 1.222 g/mL at 20 °C (lit.)
• SMILES string: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][CH]2)N(C)C
• InChI: 1S/C9H14N.C5H5.Fe/c1-8(10(2)3)9-6-4-5-7-9;1-2-4-5-3-1;/h4-8H,1-3H3;1-5H;/t8-;;/m0../s1
• InChI key: ISOLNZQTVMCEOI-JZGIKJSDSA-N

Description

Application

(S)-(−)-N,N-Dimethyl-1-ferrocenylethylamine can be used:

• As a starting material in the synthesis of chiral diferrocenylphosphine-diamines applicable in catalysis.
• As a model chiral probe in the study of enantiodiscrimination ability of chiral ionic liquids using cyclic voltammetry.

Safety Information

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 203.0 °F - closed cup
• Flash Point(C): 95 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves