258202

Hafnium(IV) chloride

98%

• Synonym(s): Hafnium tetrachloride, Tetrachlorohafnium
• Linear Formula: HfCl₄
• CAS Number: 13499-05-3
• Molecular Weight: 320.30
• EC Number: 236-826-5
• MDL number: MFCD00011034
• UNSPSC Code: 12352302
• PubChem Substance ID: 24855637
• NACRES: NA.23

Properties

• vapor pressure: 1 mmHg ( 190 °C)
• Assay: 98%
• form: powder
• mp: 432 °C (lit.)
• solubility: H₂O: decomposes(lit.)
• SMILES string: Cl[Hf](Cl)(Cl)Cl
• InChI: 1S/4ClH.Hf/h4*1H;/q;;;;+4/p-4
• InChI key: PDPJQWYGJJBYLF-UHFFFAOYSA-J

Description

General description

Hafnium(IV) chloride, also known as hafnium tetrachloride, is commonly used as a precursor in the production of hafnium metal and various hafnium compounds. Additionally, it serves as a catalyst in certain organic synthesis reactions. Due to its reactivity and sensitivity to moisture, hafnium(IV) chloride is typically handled under an inert atmosphere.

Application

Hafnium(IV) chloride can be used as:     

• A precursor in the synthesis of lithium hafnium phosphate, which is a solid electrolyte material used in lithium batteries due to its high ionic conductivity and chemical stability.      
• A catalyst in the acetalization process of various carbonyl compounds, including aldehydes and ketones.      
• A catalyst in the direct ester condensation of carboxylic acids with alcohols.    
• A high-capacity cathode material for lithium and sodium-ion batteries.

Safety Information

• Pictograms: GHS05
• Signal Word: Danger
• Hazard Statements: H290,H314
• Precautionary Statements: P234 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1
• Supplementary Hazards: EUH014
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3