Skip to Content
Merck
All Photos(2)

Documents

238090

Sigma-Aldrich

1-Bromo-4-iodobenzene

98%

Synonym(s):

4-Bromo-1-iodobenzene, 4-Bromoiodobenzene, 4-Iodo-1-bromobenzene, 4-Iodophenyl bromide, p-Bromophenyl iodide, p-Iodobromobenzene

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
BrC6H4I
CAS Number:
589-87-7
Molecular Weight:
282.90
Beilstein:
1904545
EC Number:
209-662-7
MDL number:
MFCD00001051
UNSPSC Code:
12352100
PubChem Substance ID:
24854290
NACRES:
NA.22

Quality Level

200

Assay

98%

form

solid

bp

120-122 °C/14 mmHg (lit.)

mp

89-91 °C (lit.)

SMILES string

Brc1ccc(I)cc1

InChI

1S/C6H4BrI/c7-5-1-3-6(8)4-2-5/h1-4H

InChI key

UCCUXODGPMAHRL-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Vapour pressure as a function of temperature for 1-bromo-4-iodobenzene has been studied using a diaphragm manometer and torsion mass-loss effusion.

Application

1-Bromo-4-iodobenzene has been employed:
  • as reagent for in situ desilylation and coupling of silylated alkynes
  • as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids)
  • as substrate in copper-free Sonogashira coupling in aqueous acetone
  • in synthesis of β,β,dibromostyrenes

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Representation and assessment of vapour pressure data; a novel approach applied to crystalline 1-bromo-4-chlorobenzene, 1-chloro-4-iodobenzene, and 1-bromo-4-iodobenzene.
Oonk HAJ, et al.
The Journal of Chemical Thermodynamics, 30(7), 897-907 (1998)
Synlett, 2061-2061 (2007)
Total syntheses of ent-conduramine A and ent -7-deoxypancratistatin.
Akgun H and Hudlicky T.
Tetrahedron Letters, 40(16), 3081-3084 (1999)
Synlett, 1843-1843 (2007)
Rapid bi-directional synthesis of oligo (1, 4-phenylene ethynylene) s.
Huang S and Tour JM.
Tetrahedron Letters, 40(17), 3447-3450 (1999)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service